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Ultrafast Independent N−H and N−C Bond Deformation Investigated with Resonant Inelastic X‐Ray Scattering
The femtosecond excited‐state dynamics following resonant photoexcitation enable the selective deformation of N−H and N−C chemical bonds in 2‐thiopyridone in aqueous solution with optical or X‐ray pulses. In combination with multiconfigurational quantum‐chemical calculations, the orbital‐specific el...
| Autores principales: | , , , , , , , , , , , , , , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
John Wiley and Sons Inc.
2017
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5485001/ https://www.ncbi.nlm.nih.gov/pubmed/28374523 http://dx.doi.org/10.1002/anie.201700239 |
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| author | Eckert, Sebastian Norell, Jesper Miedema, Piter S. Beye, Martin Fondell, Mattis Quevedo, Wilson Kennedy, Brian Hantschmann, Markus Pietzsch, Annette Van Kuiken, Benjamin E. Ross, Matthew Minitti, Michael P. Moeller, Stefan P. Schlotter, William F. Khalil, Munira Odelius, Michael Föhlisch, Alexander |
| author_facet | Eckert, Sebastian Norell, Jesper Miedema, Piter S. Beye, Martin Fondell, Mattis Quevedo, Wilson Kennedy, Brian Hantschmann, Markus Pietzsch, Annette Van Kuiken, Benjamin E. Ross, Matthew Minitti, Michael P. Moeller, Stefan P. Schlotter, William F. Khalil, Munira Odelius, Michael Föhlisch, Alexander |
| author_sort | Eckert, Sebastian |
| collection | PubMed |
| description | The femtosecond excited‐state dynamics following resonant photoexcitation enable the selective deformation of N−H and N−C chemical bonds in 2‐thiopyridone in aqueous solution with optical or X‐ray pulses. In combination with multiconfigurational quantum‐chemical calculations, the orbital‐specific electronic structure and its ultrafast dynamics accessed with resonant inelastic X‐ray scattering at the N 1s level using synchrotron radiation and the soft X‐ray free‐electron laser LCLS provide direct evidence for this controlled photoinduced molecular deformation and its ultrashort timescale. |
| format | Online Article Text |
| id | pubmed-5485001 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2017 |
| publisher | John Wiley and Sons Inc. |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-54850012017-07-11 Ultrafast Independent N−H and N−C Bond Deformation Investigated with Resonant Inelastic X‐Ray Scattering Eckert, Sebastian Norell, Jesper Miedema, Piter S. Beye, Martin Fondell, Mattis Quevedo, Wilson Kennedy, Brian Hantschmann, Markus Pietzsch, Annette Van Kuiken, Benjamin E. Ross, Matthew Minitti, Michael P. Moeller, Stefan P. Schlotter, William F. Khalil, Munira Odelius, Michael Föhlisch, Alexander Angew Chem Int Ed Engl Communications The femtosecond excited‐state dynamics following resonant photoexcitation enable the selective deformation of N−H and N−C chemical bonds in 2‐thiopyridone in aqueous solution with optical or X‐ray pulses. In combination with multiconfigurational quantum‐chemical calculations, the orbital‐specific electronic structure and its ultrafast dynamics accessed with resonant inelastic X‐ray scattering at the N 1s level using synchrotron radiation and the soft X‐ray free‐electron laser LCLS provide direct evidence for this controlled photoinduced molecular deformation and its ultrashort timescale. John Wiley and Sons Inc. 2017-04-04 2017-05-22 /pmc/articles/PMC5485001/ /pubmed/28374523 http://dx.doi.org/10.1002/anie.201700239 Text en © 2017 The Authors. Published by Wiley-VCH Verlag GmbH & Co. KGaA. This is an open access article under the terms of the Creative Commons Attribution‐NonCommercial‐NoDerivs (http://creativecommons.org/licenses/by-nc-nd/4.0/) License, which permits use and distribution in any medium, provided the original work is properly cited, the use is non‐commercial and no modifications or adaptations are made. |
| spellingShingle | Communications Eckert, Sebastian Norell, Jesper Miedema, Piter S. Beye, Martin Fondell, Mattis Quevedo, Wilson Kennedy, Brian Hantschmann, Markus Pietzsch, Annette Van Kuiken, Benjamin E. Ross, Matthew Minitti, Michael P. Moeller, Stefan P. Schlotter, William F. Khalil, Munira Odelius, Michael Föhlisch, Alexander Ultrafast Independent N−H and N−C Bond Deformation Investigated with Resonant Inelastic X‐Ray Scattering |
| title | Ultrafast Independent N−H and N−C Bond Deformation Investigated with Resonant Inelastic X‐Ray Scattering |
| title_full | Ultrafast Independent N−H and N−C Bond Deformation Investigated with Resonant Inelastic X‐Ray Scattering |
| title_fullStr | Ultrafast Independent N−H and N−C Bond Deformation Investigated with Resonant Inelastic X‐Ray Scattering |
| title_full_unstemmed | Ultrafast Independent N−H and N−C Bond Deformation Investigated with Resonant Inelastic X‐Ray Scattering |
| title_short | Ultrafast Independent N−H and N−C Bond Deformation Investigated with Resonant Inelastic X‐Ray Scattering |
| title_sort | ultrafast independent n−h and n−c bond deformation investigated with resonant inelastic x‐ray scattering |
| topic | Communications |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5485001/ https://www.ncbi.nlm.nih.gov/pubmed/28374523 http://dx.doi.org/10.1002/anie.201700239 |
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