A Structurally Characterized Organometallic Plutonium(IV) Complex

The blood‐red plutonocene complex Pu(1,3‐COT′′)(1,4‐COT′′) (4; COT′′=η(8)‐bis(trimethylsilyl)cyclooctatetraenyl) has been synthesized by oxidation of the anionic sandwich complex Li[Pu(1,4‐COT′′)(2)] (3) with anhydrous cobalt(II) chloride. The first crystal structure determination of an organopluton...

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Autores principales: Apostolidis, Christos, Walter, Olaf, Vogt, Jochen, Liebing, Phil, Maron, Laurent, Edelmann, Frank T.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2017
Materias:
Communications
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5485009/
https://www.ncbi.nlm.nih.gov/pubmed/28371148
http://dx.doi.org/10.1002/anie.201701858
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author Apostolidis, Christos
Walter, Olaf
Vogt, Jochen
Liebing, Phil
Maron, Laurent
Edelmann, Frank T.
author_facet Apostolidis, Christos
Walter, Olaf
Vogt, Jochen
Liebing, Phil
Maron, Laurent
Edelmann, Frank T.
author_sort Apostolidis, Christos
collection PubMed
description The blood‐red plutonocene complex Pu(1,3‐COT′′)(1,4‐COT′′) (4; COT′′=η(8)‐bis(trimethylsilyl)cyclooctatetraenyl) has been synthesized by oxidation of the anionic sandwich complex Li[Pu(1,4‐COT′′)(2)] (3) with anhydrous cobalt(II) chloride. The first crystal structure determination of an organoplutonium(IV) complex revealed an asymmetric sandwich structure for 4 where one COT′′ ring is 1,3‐substituted while the other retains the original 1,4‐substitution pattern. The electronic structure of 4 has been elucidated by a computational study, revealing a probable cause for the unexpected silyl group migration.
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spelling pubmed-54850092017-07-24 A Structurally Characterized Organometallic Plutonium(IV) Complex Apostolidis, Christos Walter, Olaf Vogt, Jochen Liebing, Phil Maron, Laurent Edelmann, Frank T. Angew Chem Int Ed Engl Communications The blood‐red plutonocene complex Pu(1,3‐COT′′)(1,4‐COT′′) (4; COT′′=η(8)‐bis(trimethylsilyl)cyclooctatetraenyl) has been synthesized by oxidation of the anionic sandwich complex Li[Pu(1,4‐COT′′)(2)] (3) with anhydrous cobalt(II) chloride. The first crystal structure determination of an organoplutonium(IV) complex revealed an asymmetric sandwich structure for 4 where one COT′′ ring is 1,3‐substituted while the other retains the original 1,4‐substitution pattern. The electronic structure of 4 has been elucidated by a computational study, revealing a probable cause for the unexpected silyl group migration. John Wiley and Sons Inc. 2017-03-30 2017-04-24 /pmc/articles/PMC5485009/ /pubmed/28371148 http://dx.doi.org/10.1002/anie.201701858 Text en © 2017 The Authors. Published by Wiley-VCH Verlag GmbH & Co. KGaA. This is an open access article under the terms of the Creative Commons Attribution (http://creativecommons.org/licenses/by/4.0/) License, which permits use, distribution and reproduction in any medium, provided the original work is properly cited.
spellingShingle Communications
Apostolidis, Christos
Walter, Olaf
Vogt, Jochen
Liebing, Phil
Maron, Laurent
Edelmann, Frank T.
A Structurally Characterized Organometallic Plutonium(IV) Complex
title A Structurally Characterized Organometallic Plutonium(IV) Complex
title_full A Structurally Characterized Organometallic Plutonium(IV) Complex
title_fullStr A Structurally Characterized Organometallic Plutonium(IV) Complex
title_full_unstemmed A Structurally Characterized Organometallic Plutonium(IV) Complex
title_short A Structurally Characterized Organometallic Plutonium(IV) Complex
title_sort structurally characterized organometallic plutonium(iv) complex
topic Communications
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5485009/
https://www.ncbi.nlm.nih.gov/pubmed/28371148
http://dx.doi.org/10.1002/anie.201701858
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