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Twisted Aromatic Frameworks: Readily Exfoliable and Solution‐Processable Two‐Dimensional Conjugated Microporous Polymers

Twisted two‐dimensional aromatic frameworks have been prepared by overcrowding the nodes with bulky and rigid substituents. The highly distorted aromatic framework with alternating out‐of‐plane substituents results in diminished interlayer interactions that favor the exfoliation and dispersion of in...

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Autores principales: Marco, A. Belen, Cortizo‐Lacalle, Diego, Perez‐Miqueo, Iñigo, Valenti, Giovanni, Boni, Alessandro, Plas, Jan, Strutyński, Karol, De Feyter, Steven, Paolucci, Francesco, Montes, Mario, Khlobystov, Andrei N., Melle‐Franco, Manuel, Mateo‐Alonso, Aurelio
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2017
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5485174/
https://www.ncbi.nlm.nih.gov/pubmed/28318084
http://dx.doi.org/10.1002/anie.201700271
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author Marco, A. Belen
Cortizo‐Lacalle, Diego
Perez‐Miqueo, Iñigo
Valenti, Giovanni
Boni, Alessandro
Plas, Jan
Strutyński, Karol
De Feyter, Steven
Paolucci, Francesco
Montes, Mario
Khlobystov, Andrei N.
Melle‐Franco, Manuel
Mateo‐Alonso, Aurelio
author_facet Marco, A. Belen
Cortizo‐Lacalle, Diego
Perez‐Miqueo, Iñigo
Valenti, Giovanni
Boni, Alessandro
Plas, Jan
Strutyński, Karol
De Feyter, Steven
Paolucci, Francesco
Montes, Mario
Khlobystov, Andrei N.
Melle‐Franco, Manuel
Mateo‐Alonso, Aurelio
author_sort Marco, A. Belen
collection PubMed
description Twisted two‐dimensional aromatic frameworks have been prepared by overcrowding the nodes with bulky and rigid substituents. The highly distorted aromatic framework with alternating out‐of‐plane substituents results in diminished interlayer interactions that favor the exfoliation and dispersion of individual layers in organic media.
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spelling pubmed-54851742017-07-21 Twisted Aromatic Frameworks: Readily Exfoliable and Solution‐Processable Two‐Dimensional Conjugated Microporous Polymers Marco, A. Belen Cortizo‐Lacalle, Diego Perez‐Miqueo, Iñigo Valenti, Giovanni Boni, Alessandro Plas, Jan Strutyński, Karol De Feyter, Steven Paolucci, Francesco Montes, Mario Khlobystov, Andrei N. Melle‐Franco, Manuel Mateo‐Alonso, Aurelio Angew Chem Int Ed Engl Communications Twisted two‐dimensional aromatic frameworks have been prepared by overcrowding the nodes with bulky and rigid substituents. The highly distorted aromatic framework with alternating out‐of‐plane substituents results in diminished interlayer interactions that favor the exfoliation and dispersion of individual layers in organic media. John Wiley and Sons Inc. 2017-03-20 2017-06-06 /pmc/articles/PMC5485174/ /pubmed/28318084 http://dx.doi.org/10.1002/anie.201700271 Text en © 2017 The Authors. Published by Wiley-VCH Verlag GmbH & Co. KGaA. This is an open access article under the terms of the Creative Commons Attribution‐NonCommercial (http://creativecommons.org/licenses/by-nc/4.0/) License, which permits use, distribution and reproduction in any medium, provided the original work is properly cited and is not used for commercial purposes.
spellingShingle Communications
Marco, A. Belen
Cortizo‐Lacalle, Diego
Perez‐Miqueo, Iñigo
Valenti, Giovanni
Boni, Alessandro
Plas, Jan
Strutyński, Karol
De Feyter, Steven
Paolucci, Francesco
Montes, Mario
Khlobystov, Andrei N.
Melle‐Franco, Manuel
Mateo‐Alonso, Aurelio
Twisted Aromatic Frameworks: Readily Exfoliable and Solution‐Processable Two‐Dimensional Conjugated Microporous Polymers
title Twisted Aromatic Frameworks: Readily Exfoliable and Solution‐Processable Two‐Dimensional Conjugated Microporous Polymers
title_full Twisted Aromatic Frameworks: Readily Exfoliable and Solution‐Processable Two‐Dimensional Conjugated Microporous Polymers
title_fullStr Twisted Aromatic Frameworks: Readily Exfoliable and Solution‐Processable Two‐Dimensional Conjugated Microporous Polymers
title_full_unstemmed Twisted Aromatic Frameworks: Readily Exfoliable and Solution‐Processable Two‐Dimensional Conjugated Microporous Polymers
title_short Twisted Aromatic Frameworks: Readily Exfoliable and Solution‐Processable Two‐Dimensional Conjugated Microporous Polymers
title_sort twisted aromatic frameworks: readily exfoliable and solution‐processable two‐dimensional conjugated microporous polymers
topic Communications
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5485174/
https://www.ncbi.nlm.nih.gov/pubmed/28318084
http://dx.doi.org/10.1002/anie.201700271
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