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Rapid water oxidation electrocatalysis by a ruthenium complex of the tripodal ligand tris(2-pyridyl)phosphine oxide

The tris(2-pyridyl)phosphine oxide (Py(3)PO) complex [Ru(Py(3)PO)(bpy)(OH(2))](2+) (bpy is 2,2′-bipyridine) is a pH-dependent water oxidation electrocatalyst that accelerates dramatically with increasing pH—up to 780 s(–1) at pH 10 (∼1 V overpotential). Despite retaining the pentakis(pyridine) ligan...

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Detalles Bibliográficos
Autores principales: Walden, Andrew G., Miller, Alexander J. M.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Royal Society of Chemistry 2015
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5488214/
https://www.ncbi.nlm.nih.gov/pubmed/28706656
http://dx.doi.org/10.1039/c5sc00032g

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