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Rapid water oxidation electrocatalysis by a ruthenium complex of the tripodal ligand tris(2-pyridyl)phosphine oxide
The tris(2-pyridyl)phosphine oxide (Py(3)PO) complex [Ru(Py(3)PO)(bpy)(OH(2))](2+) (bpy is 2,2′-bipyridine) is a pH-dependent water oxidation electrocatalyst that accelerates dramatically with increasing pH—up to 780 s(–1) at pH 10 (∼1 V overpotential). Despite retaining the pentakis(pyridine) ligan...
| Autores principales: | , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
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Royal Society of Chemistry
2015
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| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5488214/ https://www.ncbi.nlm.nih.gov/pubmed/28706656 http://dx.doi.org/10.1039/c5sc00032g |