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Supramolecular Interfacial Polymerization: A Controllable Method of Fabricating Supramolecular Polymeric Materials
A new method of supramolecular polymerization at the water–oil interface is developed. As a demonstration, an oil‐soluble supramonomer containing two thiol end groups linked by two ureidopyrimidinone units and a water‐soluble monomer bearing two maleimide end groups are employed. Supramolecular inte...
Autores principales: | , , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
John Wiley and Sons Inc.
2017
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5488215/ https://www.ncbi.nlm.nih.gov/pubmed/28480605 http://dx.doi.org/10.1002/anie.201703572 |
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author | Qin, Bo Zhang, Shuai Song, Qiao Huang, Zehuan Xu, Jiang‐Fei Zhang, Xi |
author_facet | Qin, Bo Zhang, Shuai Song, Qiao Huang, Zehuan Xu, Jiang‐Fei Zhang, Xi |
author_sort | Qin, Bo |
collection | PubMed |
description | A new method of supramolecular polymerization at the water–oil interface is developed. As a demonstration, an oil‐soluble supramonomer containing two thiol end groups linked by two ureidopyrimidinone units and a water‐soluble monomer bearing two maleimide end groups are employed. Supramolecular interfacial polymerization can be implemented by a thiol–maleimide click reaction at the water–chloroform interface to obtain supramolecular polymeric films. The glass transition temperature of such supramolecular polymers can be well‐tuned by simply changing the polymerization time and temperature. It is highly anticipated that this work will provide a facile and general approach to realize control over supramolecular polymerization by transferring the preparation of supramolecular polymers from solutions to water–oil interfaces and construct supramolecular materials with well‐defined properties. |
format | Online Article Text |
id | pubmed-5488215 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2017 |
publisher | John Wiley and Sons Inc. |
record_format | MEDLINE/PubMed |
spelling | pubmed-54882152017-07-24 Supramolecular Interfacial Polymerization: A Controllable Method of Fabricating Supramolecular Polymeric Materials Qin, Bo Zhang, Shuai Song, Qiao Huang, Zehuan Xu, Jiang‐Fei Zhang, Xi Angew Chem Int Ed Engl Communications A new method of supramolecular polymerization at the water–oil interface is developed. As a demonstration, an oil‐soluble supramonomer containing two thiol end groups linked by two ureidopyrimidinone units and a water‐soluble monomer bearing two maleimide end groups are employed. Supramolecular interfacial polymerization can be implemented by a thiol–maleimide click reaction at the water–chloroform interface to obtain supramolecular polymeric films. The glass transition temperature of such supramolecular polymers can be well‐tuned by simply changing the polymerization time and temperature. It is highly anticipated that this work will provide a facile and general approach to realize control over supramolecular polymerization by transferring the preparation of supramolecular polymers from solutions to water–oil interfaces and construct supramolecular materials with well‐defined properties. John Wiley and Sons Inc. 2017-05-24 2017-06-19 /pmc/articles/PMC5488215/ /pubmed/28480605 http://dx.doi.org/10.1002/anie.201703572 Text en © 2017 The Authors. Published by Wiley-VCH Verlag GmbH & Co. KGaA. This is an open access article under the terms of the Creative Commons Attribution‐NonCommercial (http://creativecommons.org/licenses/by-nc/4.0/) License, which permits use, distribution and reproduction in any medium, provided the original work is properly cited and is not used for commercial purposes. |
spellingShingle | Communications Qin, Bo Zhang, Shuai Song, Qiao Huang, Zehuan Xu, Jiang‐Fei Zhang, Xi Supramolecular Interfacial Polymerization: A Controllable Method of Fabricating Supramolecular Polymeric Materials |
title | Supramolecular Interfacial Polymerization: A Controllable Method of Fabricating Supramolecular Polymeric Materials |
title_full | Supramolecular Interfacial Polymerization: A Controllable Method of Fabricating Supramolecular Polymeric Materials |
title_fullStr | Supramolecular Interfacial Polymerization: A Controllable Method of Fabricating Supramolecular Polymeric Materials |
title_full_unstemmed | Supramolecular Interfacial Polymerization: A Controllable Method of Fabricating Supramolecular Polymeric Materials |
title_short | Supramolecular Interfacial Polymerization: A Controllable Method of Fabricating Supramolecular Polymeric Materials |
title_sort | supramolecular interfacial polymerization: a controllable method of fabricating supramolecular polymeric materials |
topic | Communications |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5488215/ https://www.ncbi.nlm.nih.gov/pubmed/28480605 http://dx.doi.org/10.1002/anie.201703572 |
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