Cr(i)Cl as well as Cr(+) are stabilised between two cyclic alkyl amino carbenes

Cr(i)Cl is a very unstable species. The present work describes the stabilisation of Cr(i)Cl in the low coordinate environment of cyclic alkyl(amino) carbene ligands and its synthetic application to yield an unprecedented cationic complex with a two coordinate Cr(i). One electron reduction of (cAAC)(...

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Detalles Bibliográficos
Autores principales: Samuel, Prinson P., Neufeld, Roman, Chandra Mondal, Kartik, Roesky, Herbert W., Herbst-Irmer, Regine, Stalke, Dietmar, Demeshko, Serhiy, Meyer, Franc, Rojisha, Vallyanga Chalil, De, Susmita, Parameswaran, Pattiyil, Stückl, A. Claudia, Kaim, Wolfgang, Christian, Jonathan H., Bindra, Jasleen K., Dalal, Naresh S.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Royal Society of Chemistry 2015
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5490427/
https://www.ncbi.nlm.nih.gov/pubmed/28706686
http://dx.doi.org/10.1039/c5sc00646e

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