A supramolecular strategy for tuning the energy level of naphthalenediimide: Promoted formation of radical anions with extraordinary stability

We report a supramolecular strategy to promote and stabilize the formation of naphthalenediimide (NDI) radical anions. The LUMO and HOMO energy of NDI are lowered significantly by introducing cucurbit[7]uril (CB[7]) to each side of a designed NDI molecule through supramolecular complexation. This pr...

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Detalles Bibliográficos
Autores principales: Song, Qiao, Li, Fei, Wang, Zhiqiang, Zhang, Xi
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Royal Society of Chemistry 2015
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5490429/
https://www.ncbi.nlm.nih.gov/pubmed/28706698
http://dx.doi.org/10.1039/c5sc00862j

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