Electron Spin Relaxation and Biochemical Characterization of the Hydrogenase Maturase HydF: Insights into [2Fe-2S] and [4Fe-4S] Cluster Communication and Hydrogenase Activation

[Image: see text] Nature utilizes [FeFe]-hydrogenase enzymes to catalyze the interconversion between H(2) and protons and electrons. Catalysis occurs at the H-cluster, a carbon monoxide-, cyanide-, and dithiomethylamine-coordinated 2Fe subcluster bridged via a cysteine to a [4Fe-4S] cluster. Biosynt...

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Detalles Bibliográficos
Autores principales: Shepard, Eric M., Byer, Amanda S., Aggarwal, Priyanka, Betz, Jeremiah N., Scott, Anna G., Shisler, Krista A., Usselman, Robert J., Eaton, Gareth R., Eaton, Sandra S., Broderick, Joan B.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2017
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5490485/
https://www.ncbi.nlm.nih.gov/pubmed/28525271
http://dx.doi.org/10.1021/acs.biochem.7b00169

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