Fe(iii) phytate metallogel as a prototype anhydrous, intermediate temperature proton conductor

A proton conducting metallogel [FNPA; ferric nitrate (FN)–phytic acid (PA)] is synthesized by immobilizing a protogenic ligand (phytic acid) using iron(iii) nitrate in DMF. The xerogel shows high proton conductivity of 2.4 × 10(–2) S cm(–1) at 120 °C, the best value known among all metal organic mat...

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Detalles Bibliográficos
Autores principales: Aiyappa, Harshitha Barike, Saha, Subhadeep, Wadge, Pritish, Banerjee, Rahul, Kurungot, Sreekumar
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Royal Society of Chemistry 2015
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5491955/
https://www.ncbi.nlm.nih.gov/pubmed/28706627
http://dx.doi.org/10.1039/c4sc02294g
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author Aiyappa, Harshitha Barike
Saha, Subhadeep
Wadge, Pritish
Banerjee, Rahul
Kurungot, Sreekumar
author_facet Aiyappa, Harshitha Barike
Saha, Subhadeep
Wadge, Pritish
Banerjee, Rahul
Kurungot, Sreekumar
author_sort Aiyappa, Harshitha Barike
collection PubMed
description A proton conducting metallogel [FNPA; ferric nitrate (FN)–phytic acid (PA)] is synthesized by immobilizing a protogenic ligand (phytic acid) using iron(iii) nitrate in DMF. The xerogel shows high proton conductivity of 2.4 × 10(–2) S cm(–1) at 120 °C, the best value known among all metal organic materials (MOMs). Marking the first such attempt in MOMs, an electrode made using the xerogel showed a power density of 0.94 mW cm(–2) at 0.6 V under dry fuel cell conditions.
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spelling pubmed-54919552017-07-13 Fe(iii) phytate metallogel as a prototype anhydrous, intermediate temperature proton conductor Aiyappa, Harshitha Barike Saha, Subhadeep Wadge, Pritish Banerjee, Rahul Kurungot, Sreekumar Chem Sci Chemistry A proton conducting metallogel [FNPA; ferric nitrate (FN)–phytic acid (PA)] is synthesized by immobilizing a protogenic ligand (phytic acid) using iron(iii) nitrate in DMF. The xerogel shows high proton conductivity of 2.4 × 10(–2) S cm(–1) at 120 °C, the best value known among all metal organic materials (MOMs). Marking the first such attempt in MOMs, an electrode made using the xerogel showed a power density of 0.94 mW cm(–2) at 0.6 V under dry fuel cell conditions. Royal Society of Chemistry 2015-01-01 2014-10-02 /pmc/articles/PMC5491955/ /pubmed/28706627 http://dx.doi.org/10.1039/c4sc02294g Text en This journal is © The Royal Society of Chemistry 2014 http://creativecommons.org/licenses/by-nc/3.0/ This is an Open Access article distributed under the terms of the Creative Commons Attribution-NonCommercial 3.0 Unported License (http://creativecommons.org/licenses/by-nc/3.0/) which permits unrestricted non-commercial use, distribution, and reproduction in any medium, provided the original work is properly cited.
spellingShingle Chemistry
Aiyappa, Harshitha Barike
Saha, Subhadeep
Wadge, Pritish
Banerjee, Rahul
Kurungot, Sreekumar
Fe(iii) phytate metallogel as a prototype anhydrous, intermediate temperature proton conductor
title Fe(iii) phytate metallogel as a prototype anhydrous, intermediate temperature proton conductor
title_full Fe(iii) phytate metallogel as a prototype anhydrous, intermediate temperature proton conductor
title_fullStr Fe(iii) phytate metallogel as a prototype anhydrous, intermediate temperature proton conductor
title_full_unstemmed Fe(iii) phytate metallogel as a prototype anhydrous, intermediate temperature proton conductor
title_short Fe(iii) phytate metallogel as a prototype anhydrous, intermediate temperature proton conductor
title_sort fe(iii) phytate metallogel as a prototype anhydrous, intermediate temperature proton conductor
topic Chemistry
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5491955/
https://www.ncbi.nlm.nih.gov/pubmed/28706627
http://dx.doi.org/10.1039/c4sc02294g
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