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Probing the second dehydrogenation step in ammonia-borane dehydrocoupling: characterization and reactivity of the key intermediate, B-(cyclotriborazanyl)amine-borane

While thermolysis of ammonia-borane (AB) affords a mixture of aminoborane- and iminoborane oligomers, the most selective metal-based catalysts afford exclusively cyclic iminoborane trimer (borazine) and its B–N cross-linked oligomers (polyborazylene). This catalysed dehydrogenation sequence proceeds...

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Detalles Bibliográficos
Autores principales:	Kalviri, Hassan A., Gärtner, Felix, Ye, Gang, Korobkov, Ilia, Baker, R. Tom
Formato:	Online Artículo Texto
Lenguaje:	English
Publicado:	Royal Society of Chemistry 2015
Materias:	Chemistry
Acceso en línea:	https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5491959/ https://www.ncbi.nlm.nih.gov/pubmed/28706630 http://dx.doi.org/10.1039/c4sc02710h

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