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Transient Formation and Reactivity of a High-Valent Nickel(IV) Oxido Complex

[Image: see text] A reactive high-valent dinuclear nickel(IV) oxido bridged complex is reported that can be formed at room temperature by reaction of [(L)(2)Ni(II)(2)(μ-X)(3)]X (X = Cl or Br) with NaOCl in methanol or acetonitrile (where L = 1,4,7-trimethyl-1,4,7-triazacyclononane). The unusual Ni(I...

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Detalles Bibliográficos
Autores principales:	Padamati, Sandeep K., Angelone, Davide, Draksharapu, Apparao, Primi, Gloria, Martin, David J., Tromp, Moniek, Swart, Marcel, Browne, Wesley R.
Formato:	Online Artículo Texto
Lenguaje:	English
Publicado:	American Chemical Society 2017
Acceso en línea:	https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5492195/ https://www.ncbi.nlm.nih.gov/pubmed/28581745 http://dx.doi.org/10.1021/jacs.7b04158

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