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Covalent Organic Frameworks as a Platform for Multidimensional Polymerization
[Image: see text] The simultaneous polymerization and crystallization of monomers featuring directional bonding designs provides covalent organic frameworks (COFs), which are periodic polymer networks with robust covalent bonds arranged in two- or three-dimensional topologies. The range of propertie...
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
American Chemical Society
2017
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Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5492257/ https://www.ncbi.nlm.nih.gov/pubmed/28691064 http://dx.doi.org/10.1021/acscentsci.7b00127 |
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author | Bisbey, Ryan P. Dichtel, William R. |
author_facet | Bisbey, Ryan P. Dichtel, William R. |
author_sort | Bisbey, Ryan P. |
collection | PubMed |
description | [Image: see text] The simultaneous polymerization and crystallization of monomers featuring directional bonding designs provides covalent organic frameworks (COFs), which are periodic polymer networks with robust covalent bonds arranged in two- or three-dimensional topologies. The range of properties characterized in COFs has rapidly expanded to include those of interest for heterogeneous catalysis, energy storage and photovoltaic devices, and proton-conducting membranes. Yet many of these applications will require materials quality, morphological control, and synthetic efficiency exceeding the capabilities of contemporary synthetic methods. This level of control will emerge from an improved fundamental understanding of COF nucleation and growth processes. More powerful characterization of structure and defects, improved syntheses guided by mechanistic understanding, and accessing diverse isolated forms, ranging from single crystals to thin films to colloidal suspensions, remain important frontier problems. |
format | Online Article Text |
id | pubmed-5492257 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2017 |
publisher | American Chemical Society |
record_format | MEDLINE/PubMed |
spelling | pubmed-54922572017-07-07 Covalent Organic Frameworks as a Platform for Multidimensional Polymerization Bisbey, Ryan P. Dichtel, William R. ACS Cent Sci [Image: see text] The simultaneous polymerization and crystallization of monomers featuring directional bonding designs provides covalent organic frameworks (COFs), which are periodic polymer networks with robust covalent bonds arranged in two- or three-dimensional topologies. The range of properties characterized in COFs has rapidly expanded to include those of interest for heterogeneous catalysis, energy storage and photovoltaic devices, and proton-conducting membranes. Yet many of these applications will require materials quality, morphological control, and synthetic efficiency exceeding the capabilities of contemporary synthetic methods. This level of control will emerge from an improved fundamental understanding of COF nucleation and growth processes. More powerful characterization of structure and defects, improved syntheses guided by mechanistic understanding, and accessing diverse isolated forms, ranging from single crystals to thin films to colloidal suspensions, remain important frontier problems. American Chemical Society 2017-05-19 2017-06-28 /pmc/articles/PMC5492257/ /pubmed/28691064 http://dx.doi.org/10.1021/acscentsci.7b00127 Text en Copyright © 2017 American Chemical Society This is an open access article published under an ACS AuthorChoice License (http://pubs.acs.org/page/policy/authorchoice_termsofuse.html) , which permits copying and redistribution of the article or any adaptations for non-commercial purposes. |
spellingShingle | Bisbey, Ryan P. Dichtel, William R. Covalent Organic Frameworks as a Platform for Multidimensional Polymerization |
title | Covalent Organic Frameworks as a Platform for Multidimensional
Polymerization |
title_full | Covalent Organic Frameworks as a Platform for Multidimensional
Polymerization |
title_fullStr | Covalent Organic Frameworks as a Platform for Multidimensional
Polymerization |
title_full_unstemmed | Covalent Organic Frameworks as a Platform for Multidimensional
Polymerization |
title_short | Covalent Organic Frameworks as a Platform for Multidimensional
Polymerization |
title_sort | covalent organic frameworks as a platform for multidimensional
polymerization |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5492257/ https://www.ncbi.nlm.nih.gov/pubmed/28691064 http://dx.doi.org/10.1021/acscentsci.7b00127 |
work_keys_str_mv | AT bisbeyryanp covalentorganicframeworksasaplatformformultidimensionalpolymerization AT dichtelwilliamr covalentorganicframeworksasaplatformformultidimensionalpolymerization |