An extended Tolerance Factor approach for organic–inorganic perovskites

Goldschmidt's concept of ionic Tolerance Factors was recently shown to be a valuable guideline for the preparation of new compounds within the field of organic–inorganic perovskites. Here, we extend this approach and calculate Tolerance Factors for over 2500 amine–metal–anion permutations of th...

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Detalles Bibliográficos
Autores principales: Kieslich, Gregor, Sun, Shijing, Cheetham, Anthony K.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Royal Society of Chemistry 2015
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5492664/
https://www.ncbi.nlm.nih.gov/pubmed/28706705
http://dx.doi.org/10.1039/c5sc00961h
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author Kieslich, Gregor
Sun, Shijing
Cheetham, Anthony K.
author_facet Kieslich, Gregor
Sun, Shijing
Cheetham, Anthony K.
author_sort Kieslich, Gregor
collection PubMed
description Goldschmidt's concept of ionic Tolerance Factors was recently shown to be a valuable guideline for the preparation of new compounds within the field of organic–inorganic perovskites. Here, we extend this approach and calculate Tolerance Factors for over 2500 amine–metal–anion permutations of the periodic table. The results suggest the potential existence of more than 600 undiscovered hybrid perovskites including alkaline earth metal and lanthanide based materials.
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spelling pubmed-54926642017-07-13 An extended Tolerance Factor approach for organic–inorganic perovskites Kieslich, Gregor Sun, Shijing Cheetham, Anthony K. Chem Sci Chemistry Goldschmidt's concept of ionic Tolerance Factors was recently shown to be a valuable guideline for the preparation of new compounds within the field of organic–inorganic perovskites. Here, we extend this approach and calculate Tolerance Factors for over 2500 amine–metal–anion permutations of the periodic table. The results suggest the potential existence of more than 600 undiscovered hybrid perovskites including alkaline earth metal and lanthanide based materials. Royal Society of Chemistry 2015-06-01 2015-04-14 /pmc/articles/PMC5492664/ /pubmed/28706705 http://dx.doi.org/10.1039/c5sc00961h Text en This journal is © The Royal Society of Chemistry 2015 http://creativecommons.org/licenses/by/3.0/ This is an Open Access article distributed under the terms of the Creative Commons Attribution 3.0 Unported License (http://creativecommons.org/licenses/by/3.0/) which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited.
spellingShingle Chemistry
Kieslich, Gregor
Sun, Shijing
Cheetham, Anthony K.
An extended Tolerance Factor approach for organic–inorganic perovskites
title An extended Tolerance Factor approach for organic–inorganic perovskites
title_full An extended Tolerance Factor approach for organic–inorganic perovskites
title_fullStr An extended Tolerance Factor approach for organic–inorganic perovskites
title_full_unstemmed An extended Tolerance Factor approach for organic–inorganic perovskites
title_short An extended Tolerance Factor approach for organic–inorganic perovskites
title_sort extended tolerance factor approach for organic–inorganic perovskites
topic Chemistry
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5492664/
https://www.ncbi.nlm.nih.gov/pubmed/28706705
http://dx.doi.org/10.1039/c5sc00961h
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