Stable porphyrin Zr and Hf metal–organic frameworks featuring 2.5 nm cages: high surface areas, SCSC transformations and catalyses

Two isostructural porphyrin Zr and Hf metal–organic frameworks (FJI-H6 and FJI-H7) are rationally synthesized, and are constructed from 2.5 nm cubic cages. Notably, they both possess high water and chemical stability and can undergo single-crystal to single-crystal transformations to embed Cu(2+) io...

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Detalles Bibliográficos
Autores principales: Zheng, Jun, Wu, Mingyan, Jiang, Feilong, Su, Weiping, Hong, Maochun
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Royal Society of Chemistry 2015
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5492870/
https://www.ncbi.nlm.nih.gov/pubmed/28706707
http://dx.doi.org/10.1039/c5sc00213c
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author Zheng, Jun
Wu, Mingyan
Jiang, Feilong
Su, Weiping
Hong, Maochun
author_facet Zheng, Jun
Wu, Mingyan
Jiang, Feilong
Su, Weiping
Hong, Maochun
author_sort Zheng, Jun
collection PubMed
description Two isostructural porphyrin Zr and Hf metal–organic frameworks (FJI-H6 and FJI-H7) are rationally synthesized, and are constructed from 2.5 nm cubic cages. Notably, they both possess high water and chemical stability and can undergo single-crystal to single-crystal transformations to embed Cu(2+) ions into the open porphyrin rings. FJI-H6 has a high BET surface area of 5033 m(2) g(–1). Additionally, they exhibit promising catalytic abilities to convert CO(2) and epoxides into cyclic carbonates at ambient conditions.
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spelling pubmed-54928702017-07-13 Stable porphyrin Zr and Hf metal–organic frameworks featuring 2.5 nm cages: high surface areas, SCSC transformations and catalyses Zheng, Jun Wu, Mingyan Jiang, Feilong Su, Weiping Hong, Maochun Chem Sci Chemistry Two isostructural porphyrin Zr and Hf metal–organic frameworks (FJI-H6 and FJI-H7) are rationally synthesized, and are constructed from 2.5 nm cubic cages. Notably, they both possess high water and chemical stability and can undergo single-crystal to single-crystal transformations to embed Cu(2+) ions into the open porphyrin rings. FJI-H6 has a high BET surface area of 5033 m(2) g(–1). Additionally, they exhibit promising catalytic abilities to convert CO(2) and epoxides into cyclic carbonates at ambient conditions. Royal Society of Chemistry 2015-06-01 2015-03-31 /pmc/articles/PMC5492870/ /pubmed/28706707 http://dx.doi.org/10.1039/c5sc00213c Text en This journal is © The Royal Society of Chemistry 2015 http://creativecommons.org/licenses/by/3.0/ This is an Open Access article distributed under the terms of the Creative Commons Attribution 3.0 Unported License (http://creativecommons.org/licenses/by/3.0/) which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited.
spellingShingle Chemistry
Zheng, Jun
Wu, Mingyan
Jiang, Feilong
Su, Weiping
Hong, Maochun
Stable porphyrin Zr and Hf metal–organic frameworks featuring 2.5 nm cages: high surface areas, SCSC transformations and catalyses
title Stable porphyrin Zr and Hf metal–organic frameworks featuring 2.5 nm cages: high surface areas, SCSC transformations and catalyses
title_full Stable porphyrin Zr and Hf metal–organic frameworks featuring 2.5 nm cages: high surface areas, SCSC transformations and catalyses
title_fullStr Stable porphyrin Zr and Hf metal–organic frameworks featuring 2.5 nm cages: high surface areas, SCSC transformations and catalyses
title_full_unstemmed Stable porphyrin Zr and Hf metal–organic frameworks featuring 2.5 nm cages: high surface areas, SCSC transformations and catalyses
title_short Stable porphyrin Zr and Hf metal–organic frameworks featuring 2.5 nm cages: high surface areas, SCSC transformations and catalyses
title_sort stable porphyrin zr and hf metal–organic frameworks featuring 2.5 nm cages: high surface areas, scsc transformations and catalyses
topic Chemistry
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5492870/
https://www.ncbi.nlm.nih.gov/pubmed/28706707
http://dx.doi.org/10.1039/c5sc00213c
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