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Stable porphyrin Zr and Hf metal–organic frameworks featuring 2.5 nm cages: high surface areas, SCSC transformations and catalyses
Two isostructural porphyrin Zr and Hf metal–organic frameworks (FJI-H6 and FJI-H7) are rationally synthesized, and are constructed from 2.5 nm cubic cages. Notably, they both possess high water and chemical stability and can undergo single-crystal to single-crystal transformations to embed Cu(2+) io...
Autores principales: | Zheng, Jun, Wu, Mingyan, Jiang, Feilong, Su, Weiping, Hong, Maochun |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
Royal Society of Chemistry
2015
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5492870/ https://www.ncbi.nlm.nih.gov/pubmed/28706707 http://dx.doi.org/10.1039/c5sc00213c |
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