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Chemical principles underpinning the performance of the metal–organic framework HKUST-1

A common feature of multi-functional metal–organic frameworks is a metal dimer in the form of a paddlewheel, as found in the structure of Cu(3)(btc)(2) (HKUST-1). The HKUST-1 framework demonstrates exceptional gas storage, sensing and separation, catalytic activity and, in recent studies, unpreceden...

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Autores principales: Hendon, Christopher H., Walsh, Aron
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Royal Society of Chemistry 2015
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5496192/
https://www.ncbi.nlm.nih.gov/pubmed/28706713
http://dx.doi.org/10.1039/c5sc01489a
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author Hendon, Christopher H.
Walsh, Aron
author_facet Hendon, Christopher H.
Walsh, Aron
author_sort Hendon, Christopher H.
collection PubMed
description A common feature of multi-functional metal–organic frameworks is a metal dimer in the form of a paddlewheel, as found in the structure of Cu(3)(btc)(2) (HKUST-1). The HKUST-1 framework demonstrates exceptional gas storage, sensing and separation, catalytic activity and, in recent studies, unprecedented ionic and electrical conductivity. These results are a promising step towards the real-world application of metal–organic materials. In this perspective, we discuss progress in the understanding of the electronic, magnetic and physical properties of HKUST-1, representative of the larger family of Cu···Cu containing metal–organic frameworks. We highlight the chemical interactions that give rise to its favourable properties, and which make this material well suited to a range of technological applications. From this analysis, we postulate key design principles for tailoring novel high-performance hybrid frameworks.
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spelling pubmed-54961922017-07-13 Chemical principles underpinning the performance of the metal–organic framework HKUST-1 Hendon, Christopher H. Walsh, Aron Chem Sci Chemistry A common feature of multi-functional metal–organic frameworks is a metal dimer in the form of a paddlewheel, as found in the structure of Cu(3)(btc)(2) (HKUST-1). The HKUST-1 framework demonstrates exceptional gas storage, sensing and separation, catalytic activity and, in recent studies, unprecedented ionic and electrical conductivity. These results are a promising step towards the real-world application of metal–organic materials. In this perspective, we discuss progress in the understanding of the electronic, magnetic and physical properties of HKUST-1, representative of the larger family of Cu···Cu containing metal–organic frameworks. We highlight the chemical interactions that give rise to its favourable properties, and which make this material well suited to a range of technological applications. From this analysis, we postulate key design principles for tailoring novel high-performance hybrid frameworks. Royal Society of Chemistry 2015-07-01 2015-05-11 /pmc/articles/PMC5496192/ /pubmed/28706713 http://dx.doi.org/10.1039/c5sc01489a Text en This journal is © The Royal Society of Chemistry 2015 http://creativecommons.org/licenses/by/3.0/ This article is freely available. This article is licensed under a Creative Commons Attribution 3.0 Unported Licence (CC BY 3.0)
spellingShingle Chemistry
Hendon, Christopher H.
Walsh, Aron
Chemical principles underpinning the performance of the metal–organic framework HKUST-1
title Chemical principles underpinning the performance of the metal–organic framework HKUST-1
title_full Chemical principles underpinning the performance of the metal–organic framework HKUST-1
title_fullStr Chemical principles underpinning the performance of the metal–organic framework HKUST-1
title_full_unstemmed Chemical principles underpinning the performance of the metal–organic framework HKUST-1
title_short Chemical principles underpinning the performance of the metal–organic framework HKUST-1
title_sort chemical principles underpinning the performance of the metal–organic framework hkust-1
topic Chemistry
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5496192/
https://www.ncbi.nlm.nih.gov/pubmed/28706713
http://dx.doi.org/10.1039/c5sc01489a
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