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Titanate Nanotubes Decorated Graphene Oxide Nanocomposites: Preparation, Flame Retardancy, and Photodegradation

Most polymers exhibit high flammability and poor degradability, which restrict their applications and causes serious environmental problem like “white pollution.” Thus, titanate nanotubes (TNTs) were adopted to decorate graphene oxide (GO) by a facile solution method to afford TNTs/GO nanocomposites...

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Autores principales: Sang, Bin, Li, Zhi-wei, Li, Xiao-hong, Yu, Lai-gui, Zhang, Zhi-jun
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Springer US 2017
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5498429/
https://www.ncbi.nlm.nih.gov/pubmed/28683538
http://dx.doi.org/10.1186/s11671-017-2211-9
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author Sang, Bin
Li, Zhi-wei
Li, Xiao-hong
Yu, Lai-gui
Zhang, Zhi-jun
author_facet Sang, Bin
Li, Zhi-wei
Li, Xiao-hong
Yu, Lai-gui
Zhang, Zhi-jun
author_sort Sang, Bin
collection PubMed
description Most polymers exhibit high flammability and poor degradability, which restrict their applications and causes serious environmental problem like “white pollution.” Thus, titanate nanotubes (TNTs) were adopted to decorate graphene oxide (GO) by a facile solution method to afford TNTs/GO nanocomposites with potential in improving the flame retardancy and photodegradability of flexible polyvinyl chloride (PVC). Results show that the as-prepared TNTs/GO can effectively improve the thermal stability and flame retardancy than TNTs and GO, especially, the peak heat release rate and total heat release were reduced by 20 and 29% with only 2.5 wt.% loading. And more, the TNTs/GO also improve the photodegradability of PVC compared with the neat PVC. The reasons can be attributed to synergistic flame-retardant and photocatalytic effects between TNTs and GO. The present research could contribute to paving a feasible pathway to constructing polymer-matrix composites with desired flame retardancy and photodegradability, thereby adding to the elimination of white pollution caused by polymers. ELECTRONIC SUPPLEMENTARY MATERIAL: The online version of this article (doi:10.1186/s11671-017-2211-9) contains supplementary material, which is available to authorized users.
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spelling pubmed-54984292017-07-20 Titanate Nanotubes Decorated Graphene Oxide Nanocomposites: Preparation, Flame Retardancy, and Photodegradation Sang, Bin Li, Zhi-wei Li, Xiao-hong Yu, Lai-gui Zhang, Zhi-jun Nanoscale Res Lett Nano Express Most polymers exhibit high flammability and poor degradability, which restrict their applications and causes serious environmental problem like “white pollution.” Thus, titanate nanotubes (TNTs) were adopted to decorate graphene oxide (GO) by a facile solution method to afford TNTs/GO nanocomposites with potential in improving the flame retardancy and photodegradability of flexible polyvinyl chloride (PVC). Results show that the as-prepared TNTs/GO can effectively improve the thermal stability and flame retardancy than TNTs and GO, especially, the peak heat release rate and total heat release were reduced by 20 and 29% with only 2.5 wt.% loading. And more, the TNTs/GO also improve the photodegradability of PVC compared with the neat PVC. The reasons can be attributed to synergistic flame-retardant and photocatalytic effects between TNTs and GO. The present research could contribute to paving a feasible pathway to constructing polymer-matrix composites with desired flame retardancy and photodegradability, thereby adding to the elimination of white pollution caused by polymers. ELECTRONIC SUPPLEMENTARY MATERIAL: The online version of this article (doi:10.1186/s11671-017-2211-9) contains supplementary material, which is available to authorized users. Springer US 2017-07-05 /pmc/articles/PMC5498429/ /pubmed/28683538 http://dx.doi.org/10.1186/s11671-017-2211-9 Text en © The Author(s). 2017 Open AccessThis article is distributed under the terms of the Creative Commons Attribution 4.0 International License (http://creativecommons.org/licenses/by/4.0/), which permits unrestricted use, distribution, and reproduction in any medium, provided you give appropriate credit to the original author(s) and the source, provide a link to the Creative Commons license, and indicate if changes were made.
spellingShingle Nano Express
Sang, Bin
Li, Zhi-wei
Li, Xiao-hong
Yu, Lai-gui
Zhang, Zhi-jun
Titanate Nanotubes Decorated Graphene Oxide Nanocomposites: Preparation, Flame Retardancy, and Photodegradation
title Titanate Nanotubes Decorated Graphene Oxide Nanocomposites: Preparation, Flame Retardancy, and Photodegradation
title_full Titanate Nanotubes Decorated Graphene Oxide Nanocomposites: Preparation, Flame Retardancy, and Photodegradation
title_fullStr Titanate Nanotubes Decorated Graphene Oxide Nanocomposites: Preparation, Flame Retardancy, and Photodegradation
title_full_unstemmed Titanate Nanotubes Decorated Graphene Oxide Nanocomposites: Preparation, Flame Retardancy, and Photodegradation
title_short Titanate Nanotubes Decorated Graphene Oxide Nanocomposites: Preparation, Flame Retardancy, and Photodegradation
title_sort titanate nanotubes decorated graphene oxide nanocomposites: preparation, flame retardancy, and photodegradation
topic Nano Express
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5498429/
https://www.ncbi.nlm.nih.gov/pubmed/28683538
http://dx.doi.org/10.1186/s11671-017-2211-9
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