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Titanate Nanotubes Decorated Graphene Oxide Nanocomposites: Preparation, Flame Retardancy, and Photodegradation
Most polymers exhibit high flammability and poor degradability, which restrict their applications and causes serious environmental problem like “white pollution.” Thus, titanate nanotubes (TNTs) were adopted to decorate graphene oxide (GO) by a facile solution method to afford TNTs/GO nanocomposites...
Autores principales: | , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
Springer US
2017
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5498429/ https://www.ncbi.nlm.nih.gov/pubmed/28683538 http://dx.doi.org/10.1186/s11671-017-2211-9 |
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author | Sang, Bin Li, Zhi-wei Li, Xiao-hong Yu, Lai-gui Zhang, Zhi-jun |
author_facet | Sang, Bin Li, Zhi-wei Li, Xiao-hong Yu, Lai-gui Zhang, Zhi-jun |
author_sort | Sang, Bin |
collection | PubMed |
description | Most polymers exhibit high flammability and poor degradability, which restrict their applications and causes serious environmental problem like “white pollution.” Thus, titanate nanotubes (TNTs) were adopted to decorate graphene oxide (GO) by a facile solution method to afford TNTs/GO nanocomposites with potential in improving the flame retardancy and photodegradability of flexible polyvinyl chloride (PVC). Results show that the as-prepared TNTs/GO can effectively improve the thermal stability and flame retardancy than TNTs and GO, especially, the peak heat release rate and total heat release were reduced by 20 and 29% with only 2.5 wt.% loading. And more, the TNTs/GO also improve the photodegradability of PVC compared with the neat PVC. The reasons can be attributed to synergistic flame-retardant and photocatalytic effects between TNTs and GO. The present research could contribute to paving a feasible pathway to constructing polymer-matrix composites with desired flame retardancy and photodegradability, thereby adding to the elimination of white pollution caused by polymers. ELECTRONIC SUPPLEMENTARY MATERIAL: The online version of this article (doi:10.1186/s11671-017-2211-9) contains supplementary material, which is available to authorized users. |
format | Online Article Text |
id | pubmed-5498429 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2017 |
publisher | Springer US |
record_format | MEDLINE/PubMed |
spelling | pubmed-54984292017-07-20 Titanate Nanotubes Decorated Graphene Oxide Nanocomposites: Preparation, Flame Retardancy, and Photodegradation Sang, Bin Li, Zhi-wei Li, Xiao-hong Yu, Lai-gui Zhang, Zhi-jun Nanoscale Res Lett Nano Express Most polymers exhibit high flammability and poor degradability, which restrict their applications and causes serious environmental problem like “white pollution.” Thus, titanate nanotubes (TNTs) were adopted to decorate graphene oxide (GO) by a facile solution method to afford TNTs/GO nanocomposites with potential in improving the flame retardancy and photodegradability of flexible polyvinyl chloride (PVC). Results show that the as-prepared TNTs/GO can effectively improve the thermal stability and flame retardancy than TNTs and GO, especially, the peak heat release rate and total heat release were reduced by 20 and 29% with only 2.5 wt.% loading. And more, the TNTs/GO also improve the photodegradability of PVC compared with the neat PVC. The reasons can be attributed to synergistic flame-retardant and photocatalytic effects between TNTs and GO. The present research could contribute to paving a feasible pathway to constructing polymer-matrix composites with desired flame retardancy and photodegradability, thereby adding to the elimination of white pollution caused by polymers. ELECTRONIC SUPPLEMENTARY MATERIAL: The online version of this article (doi:10.1186/s11671-017-2211-9) contains supplementary material, which is available to authorized users. Springer US 2017-07-05 /pmc/articles/PMC5498429/ /pubmed/28683538 http://dx.doi.org/10.1186/s11671-017-2211-9 Text en © The Author(s). 2017 Open AccessThis article is distributed under the terms of the Creative Commons Attribution 4.0 International License (http://creativecommons.org/licenses/by/4.0/), which permits unrestricted use, distribution, and reproduction in any medium, provided you give appropriate credit to the original author(s) and the source, provide a link to the Creative Commons license, and indicate if changes were made. |
spellingShingle | Nano Express Sang, Bin Li, Zhi-wei Li, Xiao-hong Yu, Lai-gui Zhang, Zhi-jun Titanate Nanotubes Decorated Graphene Oxide Nanocomposites: Preparation, Flame Retardancy, and Photodegradation |
title | Titanate Nanotubes Decorated Graphene Oxide Nanocomposites: Preparation, Flame Retardancy, and Photodegradation |
title_full | Titanate Nanotubes Decorated Graphene Oxide Nanocomposites: Preparation, Flame Retardancy, and Photodegradation |
title_fullStr | Titanate Nanotubes Decorated Graphene Oxide Nanocomposites: Preparation, Flame Retardancy, and Photodegradation |
title_full_unstemmed | Titanate Nanotubes Decorated Graphene Oxide Nanocomposites: Preparation, Flame Retardancy, and Photodegradation |
title_short | Titanate Nanotubes Decorated Graphene Oxide Nanocomposites: Preparation, Flame Retardancy, and Photodegradation |
title_sort | titanate nanotubes decorated graphene oxide nanocomposites: preparation, flame retardancy, and photodegradation |
topic | Nano Express |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5498429/ https://www.ncbi.nlm.nih.gov/pubmed/28683538 http://dx.doi.org/10.1186/s11671-017-2211-9 |
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