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Crystal structure of {N-[(6-bromopyridin-2-yl)(phenyl)methylidene]-2,6-dimethylaniline-κ(2) N,N′}dichloridozinc dichloromethane hemisolvate
The solvated title compound, [ZnCl(2)(C(20)H(17)BrN(2))]·0.5CH(2)Cl(2), comprises a bidentate iminopyridine ligand and two Cl atoms bound to a zinc(2+) cation in a distorted tetrahedral arrangement. The chelate bond lengths are consistent with localized C=N double bonds and a C—C single bond, as e...
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2017
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5499262/ https://www.ncbi.nlm.nih.gov/pubmed/28775854 http://dx.doi.org/10.1107/S2056989017007812 |
Sumario: | The solvated title compound, [ZnCl(2)(C(20)H(17)BrN(2))]·0.5CH(2)Cl(2), comprises a bidentate iminopyridine ligand and two Cl atoms bound to a zinc(2+) cation in a distorted tetrahedral arrangement. The chelate bond lengths are consistent with localized C=N double bonds and a C—C single bond, as expected for an unreduced ligand bound to a closed-shell transition metal cation. Apart from weak nonclassical C—H⋯Cl hydrogen bonds between the complex molecules and the disordered solvent molecules (occupancy = 0.5), no further significant intermolecular interactions are observed. |
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