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Crystal structure of {N-[(6-bromopyridin-2-yl)(phenyl)methylidene]-2,6-dimethylaniline-κ(2) N,N′}dichloridozinc dichloromethane hemisolvate
The solvated title compound, [ZnCl(2)(C(20)H(17)BrN(2))]·0.5CH(2)Cl(2), comprises a bidentate iminopyridine ligand and two Cl atoms bound to a zinc(2+) cation in a distorted tetrahedral arrangement. The chelate bond lengths are consistent with localized C=N double bonds and a C—C single bond, as e...
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Formato: | Online Artículo Texto |
Lenguaje: | English |
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International Union of Crystallography
2017
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Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5499262/ https://www.ncbi.nlm.nih.gov/pubmed/28775854 http://dx.doi.org/10.1107/S2056989017007812 |
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author | Wile, Bradley M. |
author_facet | Wile, Bradley M. |
author_sort | Wile, Bradley M. |
collection | PubMed |
description | The solvated title compound, [ZnCl(2)(C(20)H(17)BrN(2))]·0.5CH(2)Cl(2), comprises a bidentate iminopyridine ligand and two Cl atoms bound to a zinc(2+) cation in a distorted tetrahedral arrangement. The chelate bond lengths are consistent with localized C=N double bonds and a C—C single bond, as expected for an unreduced ligand bound to a closed-shell transition metal cation. Apart from weak nonclassical C—H⋯Cl hydrogen bonds between the complex molecules and the disordered solvent molecules (occupancy = 0.5), no further significant intermolecular interactions are observed. |
format | Online Article Text |
id | pubmed-5499262 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2017 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-54992622017-08-03 Crystal structure of {N-[(6-bromopyridin-2-yl)(phenyl)methylidene]-2,6-dimethylaniline-κ(2) N,N′}dichloridozinc dichloromethane hemisolvate Wile, Bradley M. Acta Crystallogr E Crystallogr Commun Research Communications The solvated title compound, [ZnCl(2)(C(20)H(17)BrN(2))]·0.5CH(2)Cl(2), comprises a bidentate iminopyridine ligand and two Cl atoms bound to a zinc(2+) cation in a distorted tetrahedral arrangement. The chelate bond lengths are consistent with localized C=N double bonds and a C—C single bond, as expected for an unreduced ligand bound to a closed-shell transition metal cation. Apart from weak nonclassical C—H⋯Cl hydrogen bonds between the complex molecules and the disordered solvent molecules (occupancy = 0.5), no further significant intermolecular interactions are observed. International Union of Crystallography 2017-06-02 /pmc/articles/PMC5499262/ /pubmed/28775854 http://dx.doi.org/10.1107/S2056989017007812 Text en © Bradley M. Wile 2017 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution (CC-BY) Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.http://creativecommons.org/licenses/by/2.0/uk/ |
spellingShingle | Research Communications Wile, Bradley M. Crystal structure of {N-[(6-bromopyridin-2-yl)(phenyl)methylidene]-2,6-dimethylaniline-κ(2) N,N′}dichloridozinc dichloromethane hemisolvate |
title | Crystal structure of {N-[(6-bromopyridin-2-yl)(phenyl)methylidene]-2,6-dimethylaniline-κ(2)
N,N′}dichloridozinc dichloromethane hemisolvate |
title_full | Crystal structure of {N-[(6-bromopyridin-2-yl)(phenyl)methylidene]-2,6-dimethylaniline-κ(2)
N,N′}dichloridozinc dichloromethane hemisolvate |
title_fullStr | Crystal structure of {N-[(6-bromopyridin-2-yl)(phenyl)methylidene]-2,6-dimethylaniline-κ(2)
N,N′}dichloridozinc dichloromethane hemisolvate |
title_full_unstemmed | Crystal structure of {N-[(6-bromopyridin-2-yl)(phenyl)methylidene]-2,6-dimethylaniline-κ(2)
N,N′}dichloridozinc dichloromethane hemisolvate |
title_short | Crystal structure of {N-[(6-bromopyridin-2-yl)(phenyl)methylidene]-2,6-dimethylaniline-κ(2)
N,N′}dichloridozinc dichloromethane hemisolvate |
title_sort | crystal structure of {n-[(6-bromopyridin-2-yl)(phenyl)methylidene]-2,6-dimethylaniline-κ(2)
n,n′}dichloridozinc dichloromethane hemisolvate |
topic | Research Communications |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5499262/ https://www.ncbi.nlm.nih.gov/pubmed/28775854 http://dx.doi.org/10.1107/S2056989017007812 |
work_keys_str_mv | AT wilebradleym crystalstructureofn6bromopyridin2ylphenylmethylidene26dimethylanilinek2nndichloridozincdichloromethanehemisolvate |