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Crystal structure of {N-[(6-bromo­pyridin-2-yl)(phen­yl)methyl­idene]-2,6-di­methyl­aniline-κ(2) N,N′}di­chlorido­zinc di­chloro­methane hemisolvate

The solvated title compound, [ZnCl(2)(C(20)H(17)BrN(2))]·0.5CH(2)Cl(2), comprises a bidentate imino­pyridine ligand and two Cl atoms bound to a zinc(2+) cation in a distorted tetra­hedral arrangement. The chelate bond lengths are consistent with localized C=N double bonds and a C—C single bond, as e...

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Autor principal: Wile, Bradley M.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2017
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5499262/
https://www.ncbi.nlm.nih.gov/pubmed/28775854
http://dx.doi.org/10.1107/S2056989017007812
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author Wile, Bradley M.
author_facet Wile, Bradley M.
author_sort Wile, Bradley M.
collection PubMed
description The solvated title compound, [ZnCl(2)(C(20)H(17)BrN(2))]·0.5CH(2)Cl(2), comprises a bidentate imino­pyridine ligand and two Cl atoms bound to a zinc(2+) cation in a distorted tetra­hedral arrangement. The chelate bond lengths are consistent with localized C=N double bonds and a C—C single bond, as expected for an unreduced ligand bound to a closed-shell transition metal cation. Apart from weak nonclassical C—H⋯Cl hydrogen bonds between the complex mol­ecules and the disordered solvent mol­ecules (occupancy = 0.5), no further significant inter­molecular inter­actions are observed.
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spelling pubmed-54992622017-08-03 Crystal structure of {N-[(6-bromo­pyridin-2-yl)(phen­yl)methyl­idene]-2,6-di­methyl­aniline-κ(2) N,N′}di­chlorido­zinc di­chloro­methane hemisolvate Wile, Bradley M. Acta Crystallogr E Crystallogr Commun Research Communications The solvated title compound, [ZnCl(2)(C(20)H(17)BrN(2))]·0.5CH(2)Cl(2), comprises a bidentate imino­pyridine ligand and two Cl atoms bound to a zinc(2+) cation in a distorted tetra­hedral arrangement. The chelate bond lengths are consistent with localized C=N double bonds and a C—C single bond, as expected for an unreduced ligand bound to a closed-shell transition metal cation. Apart from weak nonclassical C—H⋯Cl hydrogen bonds between the complex mol­ecules and the disordered solvent mol­ecules (occupancy = 0.5), no further significant inter­molecular inter­actions are observed. International Union of Crystallography 2017-06-02 /pmc/articles/PMC5499262/ /pubmed/28775854 http://dx.doi.org/10.1107/S2056989017007812 Text en © Bradley M. Wile 2017 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution (CC-BY) Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.http://creativecommons.org/licenses/by/2.0/uk/
spellingShingle Research Communications
Wile, Bradley M.
Crystal structure of {N-[(6-bromo­pyridin-2-yl)(phen­yl)methyl­idene]-2,6-di­methyl­aniline-κ(2) N,N′}di­chlorido­zinc di­chloro­methane hemisolvate
title Crystal structure of {N-[(6-bromo­pyridin-2-yl)(phen­yl)methyl­idene]-2,6-di­methyl­aniline-κ(2) N,N′}di­chlorido­zinc di­chloro­methane hemisolvate
title_full Crystal structure of {N-[(6-bromo­pyridin-2-yl)(phen­yl)methyl­idene]-2,6-di­methyl­aniline-κ(2) N,N′}di­chlorido­zinc di­chloro­methane hemisolvate
title_fullStr Crystal structure of {N-[(6-bromo­pyridin-2-yl)(phen­yl)methyl­idene]-2,6-di­methyl­aniline-κ(2) N,N′}di­chlorido­zinc di­chloro­methane hemisolvate
title_full_unstemmed Crystal structure of {N-[(6-bromo­pyridin-2-yl)(phen­yl)methyl­idene]-2,6-di­methyl­aniline-κ(2) N,N′}di­chlorido­zinc di­chloro­methane hemisolvate
title_short Crystal structure of {N-[(6-bromo­pyridin-2-yl)(phen­yl)methyl­idene]-2,6-di­methyl­aniline-κ(2) N,N′}di­chlorido­zinc di­chloro­methane hemisolvate
title_sort crystal structure of {n-[(6-bromo­pyridin-2-yl)(phen­yl)methyl­idene]-2,6-di­methyl­aniline-κ(2) n,n′}di­chlorido­zinc di­chloro­methane hemisolvate
topic Research Communications
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5499262/
https://www.ncbi.nlm.nih.gov/pubmed/28775854
http://dx.doi.org/10.1107/S2056989017007812
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