Crystal structure of [1,2-bis­(di­phenyl­phosphan­yl)benzene]­hepta­carbonyldi-μ-hydrido-(μ(3)-2,4,6-tri­methyl­phenyl­phosphin­idene)-triangulo-triruthenium

The title trinuclear ruthenium cluster, [Ru(3)(C(30)H(24)P(2))(C(9)H(11)P)(CO)(7)(μ-H)(2)], has a triangular Ru(3) core that is capped with a mesitylphosphin­idene ligand, μ(3)-PMes (Mes = mesityl = 2,4,6-tri­methyl­phen­yl). The 1,2-bis­(di­phenyl­phosphan­yl)benzene mol­ecule acts as a bidentate p...

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Detalles Bibliográficos
Autor principal: Kakizawa, Taeko
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2017
Materias:
Research Communications
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5499265/
https://www.ncbi.nlm.nih.gov/pubmed/28775857
http://dx.doi.org/10.1107/S2056989017007770
Descripción
Sumario:The title trinuclear ruthenium cluster, [Ru(3)(C(30)H(24)P(2))(C(9)H(11)P)(CO)(7)(μ-H)(2)], has a triangular Ru(3) core that is capped with a mesitylphosphin­idene ligand, μ(3)-PMes (Mes = mesityl = 2,4,6-tri­methyl­phen­yl). The 1,2-bis­(di­phenyl­phosphan­yl)benzene mol­ecule acts as a bidentate phosphine ligand via two P atoms connecting to a single Ru atom. The title compound crystallizes with two independent mol­ecules in the asymmetric unit.

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