Crystal structure of [1,2-bis­(di­phenyl­phosphan­yl)benzene]­hepta­carbonyldi-μ-hydrido-(μ(3)-2,4,6-tri­methyl­phenyl­phosphin­idene)-triangulo-triruthenium

The title trinuclear ruthenium cluster, [Ru(3)(C(30)H(24)P(2))(C(9)H(11)P)(CO)(7)(μ-H)(2)], has a triangular Ru(3) core that is capped with a mesitylphosphin­idene ligand, μ(3)-PMes (Mes = mesityl = 2,4,6-tri­methyl­phen­yl). The 1,2-bis­(di­phenyl­phosphan­yl)benzene mol­ecule acts as a bidentate p...

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Autor principal: Kakizawa, Taeko
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2017
Materias:
Research Communications
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5499265/
https://www.ncbi.nlm.nih.gov/pubmed/28775857
http://dx.doi.org/10.1107/S2056989017007770
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author Kakizawa, Taeko
author_facet Kakizawa, Taeko
author_sort Kakizawa, Taeko
collection PubMed
description The title trinuclear ruthenium cluster, [Ru(3)(C(30)H(24)P(2))(C(9)H(11)P)(CO)(7)(μ-H)(2)], has a triangular Ru(3) core that is capped with a mesitylphosphin­idene ligand, μ(3)-PMes (Mes = mesityl = 2,4,6-tri­methyl­phen­yl). The 1,2-bis­(di­phenyl­phosphan­yl)benzene mol­ecule acts as a bidentate phosphine ligand via two P atoms connecting to a single Ru atom. The title compound crystallizes with two independent mol­ecules in the asymmetric unit.
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spelling pubmed-54992652017-08-03 Crystal structure of [1,2-bis­(di­phenyl­phosphan­yl)benzene]­hepta­carbonyldi-μ-hydrido-(μ(3)-2,4,6-tri­methyl­phenyl­phosphin­idene)-triangulo-triruthenium Kakizawa, Taeko Acta Crystallogr E Crystallogr Commun Research Communications The title trinuclear ruthenium cluster, [Ru(3)(C(30)H(24)P(2))(C(9)H(11)P)(CO)(7)(μ-H)(2)], has a triangular Ru(3) core that is capped with a mesitylphosphin­idene ligand, μ(3)-PMes (Mes = mesityl = 2,4,6-tri­methyl­phen­yl). The 1,2-bis­(di­phenyl­phosphan­yl)benzene mol­ecule acts as a bidentate phosphine ligand via two P atoms connecting to a single Ru atom. The title compound crystallizes with two independent mol­ecules in the asymmetric unit. International Union of Crystallography 2017-06-02 /pmc/articles/PMC5499265/ /pubmed/28775857 http://dx.doi.org/10.1107/S2056989017007770 Text en © Taeko Kakizawa 2017 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution (CC-BY) Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.http://creativecommons.org/licenses/by/2.0/uk/
spellingShingle Research Communications
Kakizawa, Taeko
Crystal structure of [1,2-bis­(di­phenyl­phosphan­yl)benzene]­hepta­carbonyldi-μ-hydrido-(μ(3)-2,4,6-tri­methyl­phenyl­phosphin­idene)-triangulo-triruthenium
title Crystal structure of [1,2-bis­(di­phenyl­phosphan­yl)benzene]­hepta­carbonyldi-μ-hydrido-(μ(3)-2,4,6-tri­methyl­phenyl­phosphin­idene)-triangulo-triruthenium
title_full Crystal structure of [1,2-bis­(di­phenyl­phosphan­yl)benzene]­hepta­carbonyldi-μ-hydrido-(μ(3)-2,4,6-tri­methyl­phenyl­phosphin­idene)-triangulo-triruthenium
title_fullStr Crystal structure of [1,2-bis­(di­phenyl­phosphan­yl)benzene]­hepta­carbonyldi-μ-hydrido-(μ(3)-2,4,6-tri­methyl­phenyl­phosphin­idene)-triangulo-triruthenium
title_full_unstemmed Crystal structure of [1,2-bis­(di­phenyl­phosphan­yl)benzene]­hepta­carbonyldi-μ-hydrido-(μ(3)-2,4,6-tri­methyl­phenyl­phosphin­idene)-triangulo-triruthenium
title_short Crystal structure of [1,2-bis­(di­phenyl­phosphan­yl)benzene]­hepta­carbonyldi-μ-hydrido-(μ(3)-2,4,6-tri­methyl­phenyl­phosphin­idene)-triangulo-triruthenium
title_sort crystal structure of [1,2-bis­(di­phenyl­phosphan­yl)benzene]­hepta­carbonyldi-μ-hydrido-(μ(3)-2,4,6-tri­methyl­phenyl­phosphin­idene)-triangulo-triruthenium
topic Research Communications
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5499265/
https://www.ncbi.nlm.nih.gov/pubmed/28775857
http://dx.doi.org/10.1107/S2056989017007770
work_keys_str_mv AT kakizawataeko crystalstructureof12bisdiphenylphosphanylbenzeneheptacarbonyldimhydridom3246trimethylphenylphosphinidenetriangulotriruthenium

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