Crystal structure of (1E,1′E)-1,1′-(pyridine-2,6-di­yl)bis­[N-(2,3,4,5,6-penta­fluoro­phen­yl)ethan-1-imine]

The title compound, C(21)H(9)F(10)N(3), represents a potential redox non-innocent pyridine di­imine ligand system. It consists of a central pyridine ring with two penta­fluoro­phenyl substituted imine groups in positions 2 and 6. The whole mol­ecule is generated by mirror symmetry, the mirror bis­ec...

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Detalles Bibliográficos
Autores principales: Boyle, Jenna, Breakfield, Catherine, Buck, Leah, McMahon, Catherine, Babbini, Dominic C.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2017
Materias:
Research Communications
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5499267/
https://www.ncbi.nlm.nih.gov/pubmed/28775859
http://dx.doi.org/10.1107/S2056989017008040
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author Boyle, Jenna
Breakfield, Catherine
Buck, Leah
McMahon, Catherine
Babbini, Dominic C.
author_facet Boyle, Jenna
Breakfield, Catherine
Buck, Leah
McMahon, Catherine
Babbini, Dominic C.
author_sort Boyle, Jenna
collection PubMed
description The title compound, C(21)H(9)F(10)N(3), represents a potential redox non-innocent pyridine di­imine ligand system. It consists of a central pyridine ring with two penta­fluoro­phenyl substituted imine groups in positions 2 and 6. The whole mol­ecule is generated by mirror symmetry, the mirror bis­ecting the N and para-C atom of the pyridine ring. The perfluoro­phenyl ring is inclined to the pyridine ring by 73.67 (8)°. In the crystal, mol­ecules stack along the a axis, but there are no significant inter­molecular inter­actions present.
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spelling pubmed-54992672017-08-03 Crystal structure of (1E,1′E)-1,1′-(pyridine-2,6-di­yl)bis­[N-(2,3,4,5,6-penta­fluoro­phen­yl)ethan-1-imine] Boyle, Jenna Breakfield, Catherine Buck, Leah McMahon, Catherine Babbini, Dominic C. Acta Crystallogr E Crystallogr Commun Research Communications The title compound, C(21)H(9)F(10)N(3), represents a potential redox non-innocent pyridine di­imine ligand system. It consists of a central pyridine ring with two penta­fluoro­phenyl substituted imine groups in positions 2 and 6. The whole mol­ecule is generated by mirror symmetry, the mirror bis­ecting the N and para-C atom of the pyridine ring. The perfluoro­phenyl ring is inclined to the pyridine ring by 73.67 (8)°. In the crystal, mol­ecules stack along the a axis, but there are no significant inter­molecular inter­actions present. International Union of Crystallography 2017-06-02 /pmc/articles/PMC5499267/ /pubmed/28775859 http://dx.doi.org/10.1107/S2056989017008040 Text en © Boyle et al. 2017 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution (CC-BY) Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.http://creativecommons.org/licenses/by/2.0/uk/
spellingShingle Research Communications
Boyle, Jenna
Breakfield, Catherine
Buck, Leah
McMahon, Catherine
Babbini, Dominic C.
Crystal structure of (1E,1′E)-1,1′-(pyridine-2,6-di­yl)bis­[N-(2,3,4,5,6-penta­fluoro­phen­yl)ethan-1-imine]
title Crystal structure of (1E,1′E)-1,1′-(pyridine-2,6-di­yl)bis­[N-(2,3,4,5,6-penta­fluoro­phen­yl)ethan-1-imine]
title_full Crystal structure of (1E,1′E)-1,1′-(pyridine-2,6-di­yl)bis­[N-(2,3,4,5,6-penta­fluoro­phen­yl)ethan-1-imine]
title_fullStr Crystal structure of (1E,1′E)-1,1′-(pyridine-2,6-di­yl)bis­[N-(2,3,4,5,6-penta­fluoro­phen­yl)ethan-1-imine]
title_full_unstemmed Crystal structure of (1E,1′E)-1,1′-(pyridine-2,6-di­yl)bis­[N-(2,3,4,5,6-penta­fluoro­phen­yl)ethan-1-imine]
title_short Crystal structure of (1E,1′E)-1,1′-(pyridine-2,6-di­yl)bis­[N-(2,3,4,5,6-penta­fluoro­phen­yl)ethan-1-imine]
title_sort crystal structure of (1e,1′e)-1,1′-(pyridine-2,6-di­yl)bis­[n-(2,3,4,5,6-penta­fluoro­phen­yl)ethan-1-imine]
topic Research Communications
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5499267/
https://www.ncbi.nlm.nih.gov/pubmed/28775859
http://dx.doi.org/10.1107/S2056989017008040
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