C (2)-isomer of [Pd(tfd)](6) [tfd is S(2)C(2)(CF(3))(2)] as its benzene solvate: a new member of the small but growing class of homoleptic palladium(II) monodi­thio­lenes in the form of hexa­meric cubes

The title compound, hexa­kis­[μ(3)-1,2-bis­(tri­fluoro­meth­yl)ethene-1,2-di­thiol­ato]-octa­hedro-hexa­palladium(II), [Pd(C(4)F(6)S(2))](6), crystallizes as its benzene solvate, [Pd(tfd)](6)·2.5C(6)H(6), where tfd is the di­thiol­ene S(2)C(2)(CF(3))(2). The mol­ecular structure of [Pd(tfd)](6) is of the hexa­metallic cube type seen previously in three examples of hexa­meric homoleptic palladium monodi­thiol­ene structures. All structures have in common: (a) the cluster closely approximates a cube containing six Pd(II) atoms, one at the centre of each cube face; (b) 12 S atoms occupy the mid-points of all 12 cube edges, providing for each Pd(II) atom an approximately square-planar S (4) environment; (c) each S atom is part of a di­thiol­ene mol­ecule, where the size of the di­thiol­ene ligand necessitates that only sulfur atoms on adjacent cube edges can be part of the same di­thiol­ene. This general cube-type framework has so far given rise to two isomeric types: an S (6)-symmetric isomer and a C (2)-chiral type (two isomers that are enanti­omers of each other). The structure of [Pd(tfd)](6) is of the C (2)-type. Out of the 12 CF(3) groups, three are rotationally disordered over two positions. Further, we answer the question of whether additional, previously undiscovered, isomers could follow from the cube rules (a) through (c) above. An exhaustive analysis shows that no additional isomers are possible and that the list of isomers (one S (6) isomer, two C (2) enanti­omers) is complete. Each isomer type could give rise to an unlimited number of compounds if the specific di­thiol­ene used is varied.