Cargando…
Crystal structure of (5-{3-[(1,4,7,10,13-pentaoxa-16-azacyclooctadecan-16-yl)carbonylamino]phenyl}-10,15,20-triphenylporphyrinato)cobalt(II)
In the title compound, [Co(C(57)H(52)N(6)O(6))], the central Co(II) atom is coordinated by four pyrrole N atoms of the porphyrin core and one O atom of the crown ether. The complex has a distorted porphyrin core, with mean absolute core-atom displacements of 0.14 (10) (C (a)), 0.20 (10) (C (b)), 0.2...
Autores principales: | , , |
---|---|
Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2017
|
Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5499269/ https://www.ncbi.nlm.nih.gov/pubmed/28775861 http://dx.doi.org/10.1107/S2056989017007745 |
Sumario: | In the title compound, [Co(C(57)H(52)N(6)O(6))], the central Co(II) atom is coordinated by four pyrrole N atoms of the porphyrin core and one O atom of the crown ether. The complex has a distorted porphyrin core, with mean absolute core-atom displacements of 0.14 (10) (C (a)), 0.20 (10) (C (b)), 0.24 (4) (C (m)) and 0.18 (10) Å (C (av)), respectively. The axial Co—O bond length is 2.3380 (15) and the average Co—N(p) bond length is 1.968 (5) Å. Intramolecular N—H⋯O and intermolecular C—H⋯π interactions are observed. |
---|