Crystal structure of (5-{3-[(1,4,7,10,13-penta­oxa-16-aza­cyclo­octa­decan-16-yl)carbonyl­amino]­phen­yl}-10,15,20-tri­phenyl­porphyrinato)cobalt(II)

In the title compound, [Co(C(57)H(52)N(6)O(6))], the central Co(II) atom is coordinated by four pyrrole N atoms of the porphyrin core and one O atom of the crown ether. The complex has a distorted porphyrin core, with mean absolute core-atom displacements of 0.14 (10) (C (a)), 0.20 (10) (C (b)), 0.2...

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Detalles Bibliográficos
Autores principales: Wu, Qi, He, Mingrui, Li, Jianfeng
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2017
Materias:
Research Communications
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5499269/
https://www.ncbi.nlm.nih.gov/pubmed/28775861
http://dx.doi.org/10.1107/S2056989017007745
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author Wu, Qi
He, Mingrui
Li, Jianfeng
author_facet Wu, Qi
He, Mingrui
Li, Jianfeng
author_sort Wu, Qi
collection PubMed
description In the title compound, [Co(C(57)H(52)N(6)O(6))], the central Co(II) atom is coordinated by four pyrrole N atoms of the porphyrin core and one O atom of the crown ether. The complex has a distorted porphyrin core, with mean absolute core-atom displacements of 0.14 (10) (C (a)), 0.20 (10) (C (b)), 0.24 (4) (C (m)) and 0.18 (10) Å (C (av)), respectively. The axial Co—O bond length is 2.3380 (15) and the average Co—N(p) bond length is 1.968 (5) Å. Intra­molecular N—H⋯O and inter­molecular C—H⋯π inter­actions are observed.
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spelling pubmed-54992692017-08-03 Crystal structure of (5-{3-[(1,4,7,10,13-penta­oxa-16-aza­cyclo­octa­decan-16-yl)carbonyl­amino]­phen­yl}-10,15,20-tri­phenyl­porphyrinato)cobalt(II) Wu, Qi He, Mingrui Li, Jianfeng Acta Crystallogr E Crystallogr Commun Research Communications In the title compound, [Co(C(57)H(52)N(6)O(6))], the central Co(II) atom is coordinated by four pyrrole N atoms of the porphyrin core and one O atom of the crown ether. The complex has a distorted porphyrin core, with mean absolute core-atom displacements of 0.14 (10) (C (a)), 0.20 (10) (C (b)), 0.24 (4) (C (m)) and 0.18 (10) Å (C (av)), respectively. The axial Co—O bond length is 2.3380 (15) and the average Co—N(p) bond length is 1.968 (5) Å. Intra­molecular N—H⋯O and inter­molecular C—H⋯π inter­actions are observed. International Union of Crystallography 2017-06-07 /pmc/articles/PMC5499269/ /pubmed/28775861 http://dx.doi.org/10.1107/S2056989017007745 Text en © Wu et al. 2017 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution (CC-BY) Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.http://creativecommons.org/licenses/by/2.0/uk/
spellingShingle Research Communications
Wu, Qi
He, Mingrui
Li, Jianfeng
Crystal structure of (5-{3-[(1,4,7,10,13-penta­oxa-16-aza­cyclo­octa­decan-16-yl)carbonyl­amino]­phen­yl}-10,15,20-tri­phenyl­porphyrinato)cobalt(II)
title Crystal structure of (5-{3-[(1,4,7,10,13-penta­oxa-16-aza­cyclo­octa­decan-16-yl)carbonyl­amino]­phen­yl}-10,15,20-tri­phenyl­porphyrinato)cobalt(II)
title_full Crystal structure of (5-{3-[(1,4,7,10,13-penta­oxa-16-aza­cyclo­octa­decan-16-yl)carbonyl­amino]­phen­yl}-10,15,20-tri­phenyl­porphyrinato)cobalt(II)
title_fullStr Crystal structure of (5-{3-[(1,4,7,10,13-penta­oxa-16-aza­cyclo­octa­decan-16-yl)carbonyl­amino]­phen­yl}-10,15,20-tri­phenyl­porphyrinato)cobalt(II)
title_full_unstemmed Crystal structure of (5-{3-[(1,4,7,10,13-penta­oxa-16-aza­cyclo­octa­decan-16-yl)carbonyl­amino]­phen­yl}-10,15,20-tri­phenyl­porphyrinato)cobalt(II)
title_short Crystal structure of (5-{3-[(1,4,7,10,13-penta­oxa-16-aza­cyclo­octa­decan-16-yl)carbonyl­amino]­phen­yl}-10,15,20-tri­phenyl­porphyrinato)cobalt(II)
title_sort crystal structure of (5-{3-[(1,4,7,10,13-penta­oxa-16-aza­cyclo­octa­decan-16-yl)carbonyl­amino]­phen­yl}-10,15,20-tri­phenyl­porphyrinato)cobalt(ii)
topic Research Communications
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5499269/
https://www.ncbi.nlm.nih.gov/pubmed/28775861
http://dx.doi.org/10.1107/S2056989017007745
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AT lijianfeng crystalstructureof531471013pentaoxa16azacyclooctadecan16ylcarbonylaminophenyl101520triphenylporphyrinatocobaltii

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