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Crystal structure of dichlorido(1,2-phenylenediamine-κ(2) N,N′)platinum(II)
The Pt(II) atom in the title compound, [PtCl(2){(C(6)H(4))(NH(2))(2)}], lies on a twofold rotation axis and has a slightly distorted square-planar coordination environment defined by two N atoms of an 1,2-phenylenediamine ligand and two Cl(−) ions. In the crystal, the planar complex molecules are...
Autores principales: | , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2017
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Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5499279/ https://www.ncbi.nlm.nih.gov/pubmed/28775871 http://dx.doi.org/10.1107/S2056989017008477 |
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author | Konno, Yosuke Matsushita, Nobuyuki |
author_facet | Konno, Yosuke Matsushita, Nobuyuki |
author_sort | Konno, Yosuke |
collection | PubMed |
description | The Pt(II) atom in the title compound, [PtCl(2){(C(6)H(4))(NH(2))(2)}], lies on a twofold rotation axis and has a slightly distorted square-planar coordination environment defined by two N atoms of an 1,2-phenylenediamine ligand and two Cl(−) ions. In the crystal, the planar complex molecules are stacked parallel to the c axis, resulting in a columnar structure. In a column, an infinite almost straight Pt⋯Pt chain is formed, suggesting weak metal–metal interactions [Pt⋯Pt = 3.3475 (8) Å]. The crystal packing is stabilized by a three-dimensional N—H⋯Cl hydrogen-bonding network between the amino groups and the Cl ligands of adjacent molecules. |
format | Online Article Text |
id | pubmed-5499279 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2017 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-54992792017-08-03 Crystal structure of dichlorido(1,2-phenylenediamine-κ(2) N,N′)platinum(II) Konno, Yosuke Matsushita, Nobuyuki Acta Crystallogr E Crystallogr Commun Research Communications The Pt(II) atom in the title compound, [PtCl(2){(C(6)H(4))(NH(2))(2)}], lies on a twofold rotation axis and has a slightly distorted square-planar coordination environment defined by two N atoms of an 1,2-phenylenediamine ligand and two Cl(−) ions. In the crystal, the planar complex molecules are stacked parallel to the c axis, resulting in a columnar structure. In a column, an infinite almost straight Pt⋯Pt chain is formed, suggesting weak metal–metal interactions [Pt⋯Pt = 3.3475 (8) Å]. The crystal packing is stabilized by a three-dimensional N—H⋯Cl hydrogen-bonding network between the amino groups and the Cl ligands of adjacent molecules. International Union of Crystallography 2017-06-13 /pmc/articles/PMC5499279/ /pubmed/28775871 http://dx.doi.org/10.1107/S2056989017008477 Text en © Konno and Matsushita 2017 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution (CC-BY) Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.http://creativecommons.org/licenses/by/2.0/uk/ |
spellingShingle | Research Communications Konno, Yosuke Matsushita, Nobuyuki Crystal structure of dichlorido(1,2-phenylenediamine-κ(2) N,N′)platinum(II) |
title | Crystal structure of dichlorido(1,2-phenylenediamine-κ(2)
N,N′)platinum(II) |
title_full | Crystal structure of dichlorido(1,2-phenylenediamine-κ(2)
N,N′)platinum(II) |
title_fullStr | Crystal structure of dichlorido(1,2-phenylenediamine-κ(2)
N,N′)platinum(II) |
title_full_unstemmed | Crystal structure of dichlorido(1,2-phenylenediamine-κ(2)
N,N′)platinum(II) |
title_short | Crystal structure of dichlorido(1,2-phenylenediamine-κ(2)
N,N′)platinum(II) |
title_sort | crystal structure of dichlorido(1,2-phenylenediamine-κ(2)
n,n′)platinum(ii) |
topic | Research Communications |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5499279/ https://www.ncbi.nlm.nih.gov/pubmed/28775871 http://dx.doi.org/10.1107/S2056989017008477 |
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