Cargando…

Crystal structure of di­chlorido­(1,2-phenyl­enedi­amine-κ(2) N,N′)platinum(II)

The Pt(II) atom in the title compound, [PtCl(2){(C(6)H(4))(NH(2))(2)}], lies on a twofold rotation axis and has a slightly distorted square-planar coordination environment defined by two N atoms of an 1,2-phenyl­enedi­amine ligand and two Cl(−) ions. In the crystal, the planar complex mol­ecules are...

Descripción completa

Detalles Bibliográficos
Autores principales: Konno, Yosuke, Matsushita, Nobuyuki
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2017
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5499279/
https://www.ncbi.nlm.nih.gov/pubmed/28775871
http://dx.doi.org/10.1107/S2056989017008477
_version_ 1783248442580008960
author Konno, Yosuke
Matsushita, Nobuyuki
author_facet Konno, Yosuke
Matsushita, Nobuyuki
author_sort Konno, Yosuke
collection PubMed
description The Pt(II) atom in the title compound, [PtCl(2){(C(6)H(4))(NH(2))(2)}], lies on a twofold rotation axis and has a slightly distorted square-planar coordination environment defined by two N atoms of an 1,2-phenyl­enedi­amine ligand and two Cl(−) ions. In the crystal, the planar complex mol­ecules are stacked parallel to the c axis, resulting in a columnar structure. In a column, an infinite almost straight Pt⋯Pt chain is formed, suggesting weak metal–metal inter­actions [Pt⋯Pt = 3.3475 (8) Å]. The crystal packing is stabilized by a three-dimensional N—H⋯Cl hydrogen-bonding network between the amino groups and the Cl ligands of adjacent mol­ecules.
format Online
Article
Text
id pubmed-5499279
institution National Center for Biotechnology Information
language English
publishDate 2017
publisher International Union of Crystallography
record_format MEDLINE/PubMed
spelling pubmed-54992792017-08-03 Crystal structure of di­chlorido­(1,2-phenyl­enedi­amine-κ(2) N,N′)platinum(II) Konno, Yosuke Matsushita, Nobuyuki Acta Crystallogr E Crystallogr Commun Research Communications The Pt(II) atom in the title compound, [PtCl(2){(C(6)H(4))(NH(2))(2)}], lies on a twofold rotation axis and has a slightly distorted square-planar coordination environment defined by two N atoms of an 1,2-phenyl­enedi­amine ligand and two Cl(−) ions. In the crystal, the planar complex mol­ecules are stacked parallel to the c axis, resulting in a columnar structure. In a column, an infinite almost straight Pt⋯Pt chain is formed, suggesting weak metal–metal inter­actions [Pt⋯Pt = 3.3475 (8) Å]. The crystal packing is stabilized by a three-dimensional N—H⋯Cl hydrogen-bonding network between the amino groups and the Cl ligands of adjacent mol­ecules. International Union of Crystallography 2017-06-13 /pmc/articles/PMC5499279/ /pubmed/28775871 http://dx.doi.org/10.1107/S2056989017008477 Text en © Konno and Matsushita 2017 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution (CC-BY) Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.http://creativecommons.org/licenses/by/2.0/uk/
spellingShingle Research Communications
Konno, Yosuke
Matsushita, Nobuyuki
Crystal structure of di­chlorido­(1,2-phenyl­enedi­amine-κ(2) N,N′)platinum(II)
title Crystal structure of di­chlorido­(1,2-phenyl­enedi­amine-κ(2) N,N′)platinum(II)
title_full Crystal structure of di­chlorido­(1,2-phenyl­enedi­amine-κ(2) N,N′)platinum(II)
title_fullStr Crystal structure of di­chlorido­(1,2-phenyl­enedi­amine-κ(2) N,N′)platinum(II)
title_full_unstemmed Crystal structure of di­chlorido­(1,2-phenyl­enedi­amine-κ(2) N,N′)platinum(II)
title_short Crystal structure of di­chlorido­(1,2-phenyl­enedi­amine-κ(2) N,N′)platinum(II)
title_sort crystal structure of di­chlorido­(1,2-phenyl­enedi­amine-κ(2) n,n′)platinum(ii)
topic Research Communications
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5499279/
https://www.ncbi.nlm.nih.gov/pubmed/28775871
http://dx.doi.org/10.1107/S2056989017008477
work_keys_str_mv AT konnoyosuke crystalstructureofdichlorido12phenylenediaminek2nnplatinumii
AT matsushitanobuyuki crystalstructureofdichlorido12phenylenediaminek2nnplatinumii