Crystal structure of 5-[2-(9H-carbazol-9-yl)eth­yl]-1,3,4-oxa­diazole-2(3H)-thione

The title compound, C(16)H(13)N(3)OS, comprises an oxa­diazo­lethione ring bound to the N atom of an almost planar carbazole ring system (r.m.s. deviation = 0.0088 Å) through an ethyl­ene chain. The oxa­diazole ring is inclined to the the carbazole ring system by 40.71 (6)°. In the crystal, N—H⋯O, N...

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Autores principales: Simpson, Jim, Mohamed, Shaaban K., El-Emary, Talaat I., Albayati, Mustafa R.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2017
Materias:
Research Communications
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5499292/
https://www.ncbi.nlm.nih.gov/pubmed/28775884
http://dx.doi.org/10.1107/S2056989017009252
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author Simpson, Jim
Mohamed, Shaaban K.
El-Emary, Talaat I.
Albayati, Mustafa R.
author_facet Simpson, Jim
Mohamed, Shaaban K.
El-Emary, Talaat I.
Albayati, Mustafa R.
author_sort Simpson, Jim
collection PubMed
description The title compound, C(16)H(13)N(3)OS, comprises an oxa­diazo­lethione ring bound to the N atom of an almost planar carbazole ring system (r.m.s. deviation = 0.0088 Å) through an ethyl­ene chain. The oxa­diazole ring is inclined to the the carbazole ring system by 40.71 (6)°. In the crystal, N—H⋯O, N—H⋯S, C—H⋯N and C—H⋯S hydrogen bonds combine with C—H⋯π(ring) and π–π contacts to stack the mol­ecules along the b-axis direction.
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spelling pubmed-54992922017-08-03 Crystal structure of 5-[2-(9H-carbazol-9-yl)eth­yl]-1,3,4-oxa­diazole-2(3H)-thione Simpson, Jim Mohamed, Shaaban K. El-Emary, Talaat I. Albayati, Mustafa R. Acta Crystallogr E Crystallogr Commun Research Communications The title compound, C(16)H(13)N(3)OS, comprises an oxa­diazo­lethione ring bound to the N atom of an almost planar carbazole ring system (r.m.s. deviation = 0.0088 Å) through an ethyl­ene chain. The oxa­diazole ring is inclined to the the carbazole ring system by 40.71 (6)°. In the crystal, N—H⋯O, N—H⋯S, C—H⋯N and C—H⋯S hydrogen bonds combine with C—H⋯π(ring) and π–π contacts to stack the mol­ecules along the b-axis direction. International Union of Crystallography 2017-06-23 /pmc/articles/PMC5499292/ /pubmed/28775884 http://dx.doi.org/10.1107/S2056989017009252 Text en © Simpson et al. 2017 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution (CC-BY) Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.http://creativecommons.org/licenses/by/2.0/uk/
spellingShingle Research Communications
Simpson, Jim
Mohamed, Shaaban K.
El-Emary, Talaat I.
Albayati, Mustafa R.
Crystal structure of 5-[2-(9H-carbazol-9-yl)eth­yl]-1,3,4-oxa­diazole-2(3H)-thione
title Crystal structure of 5-[2-(9H-carbazol-9-yl)eth­yl]-1,3,4-oxa­diazole-2(3H)-thione
title_full Crystal structure of 5-[2-(9H-carbazol-9-yl)eth­yl]-1,3,4-oxa­diazole-2(3H)-thione
title_fullStr Crystal structure of 5-[2-(9H-carbazol-9-yl)eth­yl]-1,3,4-oxa­diazole-2(3H)-thione
title_full_unstemmed Crystal structure of 5-[2-(9H-carbazol-9-yl)eth­yl]-1,3,4-oxa­diazole-2(3H)-thione
title_short Crystal structure of 5-[2-(9H-carbazol-9-yl)eth­yl]-1,3,4-oxa­diazole-2(3H)-thione
title_sort crystal structure of 5-[2-(9h-carbazol-9-yl)eth­yl]-1,3,4-oxa­diazole-2(3h)-thione
topic Research Communications
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5499292/
https://www.ncbi.nlm.nih.gov/pubmed/28775884
http://dx.doi.org/10.1107/S2056989017009252
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