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Crystal structure of (−)-(S)-4-[(2S,3S,4S,Z)-3-hydroxy-4-methylhept-5-en-2-yl]-1,3-dioxolan-2-one
The title compound, C(11)H(18)O(4), consists of an anti,anti,anti-stereotetrad with a 1,2-carbonate and an alkene motif. The molecule displays a common zigzag conformation. The five-membered ring has a twisted conformation on the C—C bond. In the crystal, a strong intermolecular hydrogen bond bet...
Autores principales: | , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2017
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5499293/ https://www.ncbi.nlm.nih.gov/pubmed/28775885 http://dx.doi.org/10.1107/S2056989017009318 |
Sumario: | The title compound, C(11)H(18)O(4), consists of an anti,anti,anti-stereotetrad with a 1,2-carbonate and an alkene motif. The molecule displays a common zigzag conformation. The five-membered ring has a twisted conformation on the C—C bond. In the crystal, a strong intermolecular hydrogen bond between the hydroxy group and the carboxylate moiety from an adjacent molecule forms chains propagating along the b-axis direction. The absolute structure of the molecule in the crystal was determined by resonant scattering [Flack parameter = 0.05 (6)]. |
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