Magnetic MOF microreactors for recyclable size-selective biocatalysis

In this contribution we report a synthetic strategy for the encapsulation of functional biomolecules within MOF-based microcapsules. We employ an agarose hydrogel droplet Pickering-stabilised by UiO-66 and magnetite nanoparticles as a template around which to deposit a hierarchically structured ZIF-...

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Detalles Bibliográficos
Autores principales: Huo, Jia, Aguilera-Sigalat, Jordi, El-Hankari, Samir, Bradshaw, Darren
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Royal Society of Chemistry 2015
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5501100/
https://www.ncbi.nlm.nih.gov/pubmed/28717454
http://dx.doi.org/10.1039/c4sc03367a
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author Huo, Jia
Aguilera-Sigalat, Jordi
El-Hankari, Samir
Bradshaw, Darren
author_facet Huo, Jia
Aguilera-Sigalat, Jordi
El-Hankari, Samir
Bradshaw, Darren
author_sort Huo, Jia
collection PubMed
description In this contribution we report a synthetic strategy for the encapsulation of functional biomolecules within MOF-based microcapsules. We employ an agarose hydrogel droplet Pickering-stabilised by UiO-66 and magnetite nanoparticles as a template around which to deposit a hierarchically structured ZIF-8 shell. The resulting microcapsules are robust, highly microporous and readily attracted to a magnet, where the hydrogel core provides a facile means to encapsulate enzymes for recyclable size-selective biocatalysis.
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spelling pubmed-55011002017-07-17 Magnetic MOF microreactors for recyclable size-selective biocatalysis Huo, Jia Aguilera-Sigalat, Jordi El-Hankari, Samir Bradshaw, Darren Chem Sci Chemistry In this contribution we report a synthetic strategy for the encapsulation of functional biomolecules within MOF-based microcapsules. We employ an agarose hydrogel droplet Pickering-stabilised by UiO-66 and magnetite nanoparticles as a template around which to deposit a hierarchically structured ZIF-8 shell. The resulting microcapsules are robust, highly microporous and readily attracted to a magnet, where the hydrogel core provides a facile means to encapsulate enzymes for recyclable size-selective biocatalysis. Royal Society of Chemistry 2015-03-01 2014-12-17 /pmc/articles/PMC5501100/ /pubmed/28717454 http://dx.doi.org/10.1039/c4sc03367a Text en This journal is © The Royal Society of Chemistry 2014 http://creativecommons.org/licenses/by/3.0/ This is an Open Access article distributed under the terms of the Creative Commons Attribution 3.0 Unported License (http://creativecommons.org/licenses/by/3.0/) which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited.
spellingShingle Chemistry
Huo, Jia
Aguilera-Sigalat, Jordi
El-Hankari, Samir
Bradshaw, Darren
Magnetic MOF microreactors for recyclable size-selective biocatalysis
title Magnetic MOF microreactors for recyclable size-selective biocatalysis
title_full Magnetic MOF microreactors for recyclable size-selective biocatalysis
title_fullStr Magnetic MOF microreactors for recyclable size-selective biocatalysis
title_full_unstemmed Magnetic MOF microreactors for recyclable size-selective biocatalysis
title_short Magnetic MOF microreactors for recyclable size-selective biocatalysis
title_sort magnetic mof microreactors for recyclable size-selective biocatalysis
topic Chemistry
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5501100/
https://www.ncbi.nlm.nih.gov/pubmed/28717454
http://dx.doi.org/10.1039/c4sc03367a
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AT elhankarisamir magneticmofmicroreactorsforrecyclablesizeselectivebiocatalysis
AT bradshawdarren magneticmofmicroreactorsforrecyclablesizeselectivebiocatalysis

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