Double-walled pyr topology networks from a novel fluoride-bridged heptanuclear metal cluster

Two isostructural metal–organic materials, Tripp-1-M (Tripp = 2,4,6-tris(4-pyridyl)pyridine; M = Co, Ni), that exhibit binodal 3,6-connected pyr network topology have been prepared and characterized. Tripp-1-M are based upon a novel M(7)F(12) (2+) cluster that possesses 12 connection points but, bec...

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Detalles Bibliográficos
Autores principales: Chen, Kai-Jie, Perry IV, John J., Scott, Hayley S., Yang, Qing-Yuan, Zaworotko, Michael J.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Royal Society of Chemistry 2015
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5502393/
https://www.ncbi.nlm.nih.gov/pubmed/28717485
http://dx.doi.org/10.1039/c5sc01515d
Descripción
Sumario:Two isostructural metal–organic materials, Tripp-1-M (Tripp = 2,4,6-tris(4-pyridyl)pyridine; M = Co, Ni), that exhibit binodal 3,6-connected pyr network topology have been prepared and characterized. Tripp-1-M are based upon a novel M(7)F(12) (2+) cluster that possesses 12 connection points but, because of double cross-linking by 3-connected Tripp ligands, it functions as a 6-connected supermolecular building block (SBB).

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