Double-walled pyr topology networks from a novel fluoride-bridged heptanuclear metal cluster

Two isostructural metal–organic materials, Tripp-1-M (Tripp = 2,4,6-tris(4-pyridyl)pyridine; M = Co, Ni), that exhibit binodal 3,6-connected pyr network topology have been prepared and characterized. Tripp-1-M are based upon a novel M(7)F(12) (2+) cluster that possesses 12 connection points but, bec...

Descripción completa

Detalles Bibliográficos
Autores principales: Chen, Kai-Jie, Perry IV, John J., Scott, Hayley S., Yang, Qing-Yuan, Zaworotko, Michael J.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Royal Society of Chemistry 2015
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5502393/
https://www.ncbi.nlm.nih.gov/pubmed/28717485
http://dx.doi.org/10.1039/c5sc01515d
_version_ 1783248946508857344
author Chen, Kai-Jie
Perry IV, John J.
Scott, Hayley S.
Yang, Qing-Yuan
Zaworotko, Michael J.
author_facet Chen, Kai-Jie
Perry IV, John J.
Scott, Hayley S.
Yang, Qing-Yuan
Zaworotko, Michael J.
author_sort Chen, Kai-Jie
collection PubMed
description Two isostructural metal–organic materials, Tripp-1-M (Tripp = 2,4,6-tris(4-pyridyl)pyridine; M = Co, Ni), that exhibit binodal 3,6-connected pyr network topology have been prepared and characterized. Tripp-1-M are based upon a novel M(7)F(12) (2+) cluster that possesses 12 connection points but, because of double cross-linking by 3-connected Tripp ligands, it functions as a 6-connected supermolecular building block (SBB).
format Online
Article
Text
id pubmed-5502393
institution National Center for Biotechnology Information
language English
publishDate 2015
publisher Royal Society of Chemistry
record_format MEDLINE/PubMed
spelling pubmed-55023932017-07-17 Double-walled pyr topology networks from a novel fluoride-bridged heptanuclear metal cluster Chen, Kai-Jie Perry IV, John J. Scott, Hayley S. Yang, Qing-Yuan Zaworotko, Michael J. Chem Sci Chemistry Two isostructural metal–organic materials, Tripp-1-M (Tripp = 2,4,6-tris(4-pyridyl)pyridine; M = Co, Ni), that exhibit binodal 3,6-connected pyr network topology have been prepared and characterized. Tripp-1-M are based upon a novel M(7)F(12) (2+) cluster that possesses 12 connection points but, because of double cross-linking by 3-connected Tripp ligands, it functions as a 6-connected supermolecular building block (SBB). Royal Society of Chemistry 2015-08-01 2015-05-22 /pmc/articles/PMC5502393/ /pubmed/28717485 http://dx.doi.org/10.1039/c5sc01515d Text en This journal is © The Royal Society of Chemistry 2015 http://creativecommons.org/licenses/by/3.0/ This is an Open Access article distributed under the terms of the Creative Commons Attribution 3.0 Unported License (http://creativecommons.org/licenses/by/3.0/) which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited.
spellingShingle Chemistry
Chen, Kai-Jie
Perry IV, John J.
Scott, Hayley S.
Yang, Qing-Yuan
Zaworotko, Michael J.
Double-walled pyr topology networks from a novel fluoride-bridged heptanuclear metal cluster
title Double-walled pyr topology networks from a novel fluoride-bridged heptanuclear metal cluster
title_full Double-walled pyr topology networks from a novel fluoride-bridged heptanuclear metal cluster
title_fullStr Double-walled pyr topology networks from a novel fluoride-bridged heptanuclear metal cluster
title_full_unstemmed Double-walled pyr topology networks from a novel fluoride-bridged heptanuclear metal cluster
title_short Double-walled pyr topology networks from a novel fluoride-bridged heptanuclear metal cluster
title_sort double-walled pyr topology networks from a novel fluoride-bridged heptanuclear metal cluster
topic Chemistry
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5502393/
https://www.ncbi.nlm.nih.gov/pubmed/28717485
http://dx.doi.org/10.1039/c5sc01515d
work_keys_str_mv AT chenkaijie doublewalledpyrtopologynetworksfromanovelfluoridebridgedheptanuclearmetalcluster
AT perryivjohnj doublewalledpyrtopologynetworksfromanovelfluoridebridgedheptanuclearmetalcluster
AT scotthayleys doublewalledpyrtopologynetworksfromanovelfluoridebridgedheptanuclearmetalcluster
AT yangqingyuan doublewalledpyrtopologynetworksfromanovelfluoridebridgedheptanuclearmetalcluster
AT zaworotkomichaelj doublewalledpyrtopologynetworksfromanovelfluoridebridgedheptanuclearmetalcluster

Ejemplares similares