Effect of Cooling Rate on Morphology of TiAl(3) Particles in Al–4Ti Master Alloy

The Al–4Ti master alloy was fabricated by aluminum (Al) and sponge titanium particle in a resistance furnace at different cooling rates. This work aims to investigate the relationship between the cooling rate and morphology of TiAl(3). The microstructure and composition of master alloys at different cooling rates were characterized and analyzed by optical microscopy (OM), X-ray diffraction (XRD), differential scanning calorimetry (DSC), and SEM with energy dispersive spectroscopy (EDS). The results showed that various morphologies of TiAl(3) particles in the Al–4Ti master alloy could be acquired at different cooling rates. Petal-like, blocky, and flake-like TiAl(3) particles in the Al–4Ti master alloy were respectively acquired at the cooling rates of 3.36 K/s, 2.57 K/s, and 0.31 K/s. It was also found that the morphology of TiAl(3) particles in the prepared master alloy changed from petal-like to blocky, then finally to flake-like, with the decrease of cooling rate. In addition, the morphology of the TiAl(3) particles has no effect on the phase inversion temperature of Al–4Ti master alloy.