The role of the 5f valence orbitals of early actinides in chemical bonding

One of the long standing debates in actinide chemistry is the level of localization and participation of the actinide 5f valence orbitals in covalent bonds across the actinide series. Here we illuminate the role of the 5f valence orbitals of uranium, neptunium and plutonium in chemical bonding using...

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Detalles Bibliográficos
Autores principales: Vitova, T., Pidchenko, I., Fellhauer, D., Bagus, P. S., Joly, Y., Pruessmann, T., Bahl, S., Gonzalez-Robles, E., Rothe, J., Altmaier, M., Denecke, M. A., Geckeis, H.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Nature Publishing Group 2017
Materias:
Article
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5504295/
https://www.ncbi.nlm.nih.gov/pubmed/28681848
http://dx.doi.org/10.1038/ncomms16053

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