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Pt nanohelices with highly ordered horizontal pore channels as enhanced photothermal materials

Recent studies have further demonstrated that the conjugation of noble metal helical nanostructures could alter their optical and catalytic activities. However, the intrinsic isotropic crystal growth of Pt makes the synthesis of high-quality Pt NCs with unique porous or branched nanostructures diffi...

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Detalles Bibliográficos
Autores principales: Song, Shuyan, Wang, Xiao, Li, Sheling, Wang, Zhuo, Zhu, Qi, Zhang, Hongjie
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Royal Society of Chemistry 2015
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5507185/
https://www.ncbi.nlm.nih.gov/pubmed/28757957
http://dx.doi.org/10.1039/c5sc01686j
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author Song, Shuyan
Wang, Xiao
Li, Sheling
Wang, Zhuo
Zhu, Qi
Zhang, Hongjie
author_facet Song, Shuyan
Wang, Xiao
Li, Sheling
Wang, Zhuo
Zhu, Qi
Zhang, Hongjie
author_sort Song, Shuyan
collection PubMed
description Recent studies have further demonstrated that the conjugation of noble metal helical nanostructures could alter their optical and catalytic activities. However, the intrinsic isotropic crystal growth of Pt makes the synthesis of high-quality Pt NCs with unique porous or branched nanostructures difficult. In this work, a new, powerful capping agent, N,N-dimethyloctadecylammonium bromide acetate sodium, was synthesized and used to coordinate Pt ions, slowing down the reaction rate. As a result, in aqueous solution, Pt nanohelices with highly ordered horizontal pore channels were successfully fabricated. Importantly, the Pt nanohelices were composed of several sub-2 nm Pt nanowires coiled together around a central point. The as-obtained samples exhibited enhanced photothermal properties compared with the classic Pt nanoparticles.
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spelling pubmed-55071852017-07-28 Pt nanohelices with highly ordered horizontal pore channels as enhanced photothermal materials Song, Shuyan Wang, Xiao Li, Sheling Wang, Zhuo Zhu, Qi Zhang, Hongjie Chem Sci Chemistry Recent studies have further demonstrated that the conjugation of noble metal helical nanostructures could alter their optical and catalytic activities. However, the intrinsic isotropic crystal growth of Pt makes the synthesis of high-quality Pt NCs with unique porous or branched nanostructures difficult. In this work, a new, powerful capping agent, N,N-dimethyloctadecylammonium bromide acetate sodium, was synthesized and used to coordinate Pt ions, slowing down the reaction rate. As a result, in aqueous solution, Pt nanohelices with highly ordered horizontal pore channels were successfully fabricated. Importantly, the Pt nanohelices were composed of several sub-2 nm Pt nanowires coiled together around a central point. The as-obtained samples exhibited enhanced photothermal properties compared with the classic Pt nanoparticles. Royal Society of Chemistry 2015-11-01 2015-07-23 /pmc/articles/PMC5507185/ /pubmed/28757957 http://dx.doi.org/10.1039/c5sc01686j Text en This journal is © The Royal Society of Chemistry 2015 http://creativecommons.org/licenses/by/3.0/ This article is freely available. This article is licensed under a Creative Commons Attribution 3.0 Unported Licence (CC BY 3.0)
spellingShingle Chemistry
Song, Shuyan
Wang, Xiao
Li, Sheling
Wang, Zhuo
Zhu, Qi
Zhang, Hongjie
Pt nanohelices with highly ordered horizontal pore channels as enhanced photothermal materials
title Pt nanohelices with highly ordered horizontal pore channels as enhanced photothermal materials
title_full Pt nanohelices with highly ordered horizontal pore channels as enhanced photothermal materials
title_fullStr Pt nanohelices with highly ordered horizontal pore channels as enhanced photothermal materials
title_full_unstemmed Pt nanohelices with highly ordered horizontal pore channels as enhanced photothermal materials
title_short Pt nanohelices with highly ordered horizontal pore channels as enhanced photothermal materials
title_sort pt nanohelices with highly ordered horizontal pore channels as enhanced photothermal materials
topic Chemistry
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5507185/
https://www.ncbi.nlm.nih.gov/pubmed/28757957
http://dx.doi.org/10.1039/c5sc01686j
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