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Advanced 1,1-carboboration reactions with pentafluorophenylboranes
The 1,1 carboboration reaction of a variety of metal-substituted alkynes with simple trialkylboranes R(3)B yields the respective alkenylboranes (Wrackmeyer reaction). The use of the strongly electrophilic R-B(C(6)F(5))(2) reagents allows for much milder reaction conditions and gives good yields of t...
| Autores principales: | , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
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Royal Society of Chemistry
2016
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| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5508682/ https://www.ncbi.nlm.nih.gov/pubmed/28757997 http://dx.doi.org/10.1039/c5sc03282b |