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π-extended [12]cycloparaphenylenes: from a hexaphenylbenzene cyclohexamer to its unexpected C (2)-symmetric congener

The synthesis of π-extended [12]cycloparaphenylene (CPP) derivatives from a kinked triangular macrocycle is presented. Depending on the reaction conditions for reductive aromatization, either a hexaphenylbenzene cyclohexamer or its C (2)-symmetric congener was obtained. Their structures were confirm...

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Detalles Bibliográficos
Autores principales: Golling, Florian E., Osella, Silvio, Quernheim, Martin, Wagner, Manfred, Beljonne, David, Müllen, Klaus
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Royal Society of Chemistry 2015
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5510010/
https://www.ncbi.nlm.nih.gov/pubmed/28757981
http://dx.doi.org/10.1039/c5sc02547h