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Addition of aluminium, zinc and magnesium hydrides to rhodium(iii)
We report the addition of M–H bonds (M = Al, Zn, Mg) to a Rh(iii) intermediate generated from the reductive elimination of triethylsilane from [Cp*Rh(H)(2)(SiEt(3))(2)]. A series of new heterobimetallic complexes possessing Rh–M bonds have been isolated and characterised by a number of spectroscopic...
| Autores principales: | , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
Royal Society of Chemistry
2015
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5510526/ https://www.ncbi.nlm.nih.gov/pubmed/28757949 http://dx.doi.org/10.1039/c5sc01309g |