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The approach to 4d/4f-polyphosphides

The first 4d/4f polyphosphides were obtained by reaction of the divalent metallocenes [Cp*(2)Ln(thf)(2)] (Ln = Sm, Yb) with [{CpMo(CO)(2)}(2)(μ,η(2:2)-P(2))] or [Cp*Mo(CO)(2)(η(3)-P(3))]. Treatment of [Cp*(2)Ln(thf)(2)] (Ln = Sm, Yb) with [{CpMo(CO)(2)}(2)(μ,η(2:2)-P(2))] gave the 16-membered bicycl...

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Detalles Bibliográficos
Autores principales: Arleth, Nicholas, Gamer, Michael T., Köppe, Ralf, Pushkarevsky, Nikolay A., Konchenko, Sergey N., Fleischmann, Martin, Bodensteiner, Michael, Scheer, Manfred, Roesky, Peter W.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Royal Society of Chemistry 2015
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5512014/
https://www.ncbi.nlm.nih.gov/pubmed/28757983
http://dx.doi.org/10.1039/c5sc02252e

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