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Discovery of low energy pathways to metal-mediated B[double bond, length as m-dash]N bond reduction guided by computation and experiment

This manuscript describes a combination of DFT calculations and experiments to assess the reduction of borazines (B–N heterocycles) by η(6)-coordination to Cr(CO)(3) or [Mn(CO)(3)](+) fragments. The energy requirements for borazine reduction are established as well as the extent to which coordinatio...

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Detalles Bibliográficos
Autores principales:	Carter, Tyler J., Heiden, Zachariah M., Szymczak, Nathaniel K.
Formato:	Online Artículo Texto
Lenguaje:	English
Publicado:	Royal Society of Chemistry 2015
Materias:	Chemistry
Acceso en línea:	https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5512141/ https://www.ncbi.nlm.nih.gov/pubmed/28757986 http://dx.doi.org/10.1039/c5sc02348c

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