Mixed valence mono- and hetero-metallic grid catenanes

Here, we report on the multicomponent self-assembly and single crystal X-ray diffraction study of a series of three interlocked mixed valence mono- and hetero-metallic [2]-catenanes made of [2 × 2] metallo-grids. They show unique structural features and highlight the essential roles of both the Cu(i...

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Autores principales: Giri, Chandan, Topić, Filip, Cametti, Massimo, Rissanen, Kari
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Royal Society of Chemistry 2015
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5512231/
https://www.ncbi.nlm.nih.gov/pubmed/28757953
http://dx.doi.org/10.1039/c5sc01851j
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author Giri, Chandan
Topić, Filip
Cametti, Massimo
Rissanen, Kari
author_facet Giri, Chandan
Topić, Filip
Cametti, Massimo
Rissanen, Kari
author_sort Giri, Chandan
collection PubMed
description Here, we report on the multicomponent self-assembly and single crystal X-ray diffraction study of a series of three interlocked mixed valence mono- and hetero-metallic [2]-catenanes made of [2 × 2] metallo-grids. They show unique structural features and highlight the essential roles of both the Cu(ii)/Cu(i) pair and of the conformationally adaptable organic ligands for achieving catenation of grids.
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spelling pubmed-55122312017-07-28 Mixed valence mono- and hetero-metallic grid catenanes Giri, Chandan Topić, Filip Cametti, Massimo Rissanen, Kari Chem Sci Chemistry Here, we report on the multicomponent self-assembly and single crystal X-ray diffraction study of a series of three interlocked mixed valence mono- and hetero-metallic [2]-catenanes made of [2 × 2] metallo-grids. They show unique structural features and highlight the essential roles of both the Cu(ii)/Cu(i) pair and of the conformationally adaptable organic ligands for achieving catenation of grids. Royal Society of Chemistry 2015-10-01 2015-06-30 /pmc/articles/PMC5512231/ /pubmed/28757953 http://dx.doi.org/10.1039/c5sc01851j Text en This journal is © The Royal Society of Chemistry 2015 https://creativecommons.org/licenses/by/3.0/This is an Open Access article distributed under the terms of the Creative Commons Attribution 3.0 Unported License (http://creativecommons.org/licenses/by/3.0/ (https://creativecommons.org/licenses/by/3.0/) ) which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited.
spellingShingle Chemistry
Giri, Chandan
Topić, Filip
Cametti, Massimo
Rissanen, Kari
Mixed valence mono- and hetero-metallic grid catenanes
title Mixed valence mono- and hetero-metallic grid catenanes
title_full Mixed valence mono- and hetero-metallic grid catenanes
title_fullStr Mixed valence mono- and hetero-metallic grid catenanes
title_full_unstemmed Mixed valence mono- and hetero-metallic grid catenanes
title_short Mixed valence mono- and hetero-metallic grid catenanes
title_sort mixed valence mono- and hetero-metallic grid catenanes
topic Chemistry
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5512231/
https://www.ncbi.nlm.nih.gov/pubmed/28757953
http://dx.doi.org/10.1039/c5sc01851j
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AT topicfilip mixedvalencemonoandheterometallicgridcatenanes
AT camettimassimo mixedvalencemonoandheterometallicgridcatenanes
AT rissanenkari mixedvalencemonoandheterometallicgridcatenanes

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