Au(I)Cl-bound N-heterocyclic carbene ligands form MII4(LAuCl)(6) integrally gilded cages

The incorporation of an N-heterocyclic carbene (NHC) moiety into a self-assembled MII4L(6) cage framework required the NHC first to be metallated with gold(i). Bimetallic cages could then be constructed using zinc(ii) and cadmium(ii) templates, showing weak luminescence. The cages were destroyed by...

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Detalles Bibliográficos
Autores principales: Ramsay, William J., Foster, Jonathan A., Moore, Katharine L., Ronson, Tanya K., Mirgalet, Raphaël J., Jefferson, David A., Nitschke, Jonathan R.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Royal Society of Chemistry 2015
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5512534/
https://www.ncbi.nlm.nih.gov/pubmed/28757991
http://dx.doi.org/10.1039/c5sc03065j

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5512534/
https://www.ncbi.nlm.nih.gov/pubmed/28757991
http://dx.doi.org/10.1039/c5sc03065j

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