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Enantioselective γ-borylation of unsaturated amides and stereoretentive Suzuki–Miyaura cross-coupling
The rhodium-catalyzed, directed catalytic asymmetric hydroboration of γ,δ-unsaturated amides affords a direct route to chiral acyclic secondary γ-borylated carbonyl derivatives in high enantiomeric purity. In contrast to a similar β-borylated amide derivative, the γ-borylated amide undergoes Suzuki–...
| Autores principales: | , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
Royal Society of Chemistry
2017
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| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5514528/ https://www.ncbi.nlm.nih.gov/pubmed/28758006 http://dx.doi.org/10.1039/c7sc01093a |