Scanning Tunneling Spectroscope Use in Electrocatalysis Testing

The relationship between the electrocatalytic properties of an electrode and its ability to transfer electrons between the electrode and a metallic tip in a scanning tunneling microscope (STM) is investigated. The alkaline oxygen evolution reaction (OER) was used as a test reaction with four different metallic glasses, Ni(78)Si(8)B(14), Ni(70)Mo(20)Si(5)B(5), Ni(58)Co(20)Si(10)B(12), and Ni(25)Co(50)Si(15)B(10), as electrodes. The electrocatalytic properties of the electrodes were determined. The electrode surfaces were then investigated with an STM. A clear relationship between the catalytic activity of an electrode toward the OER and its tunneling characteristics was found. The use of a scanning tunneling spectroscope (STS) in electrocatalytic testing may increase the efficiency of the optimization of electrochemical processes.