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Many Mg–Mg bonds form the core of the Mg(16)Cp*8Br(4)K cluster anion: the key to a reassessment of the Grignard reagent (GR) formation process?
It caused a sensation eight years ago, when the first room temperature stable molecular compound with a Mg–Mg bond (LMgMgL, L = chelating ligand) containing magnesium in the oxidation state +1 was prepared. Here, we report the preparation of a [Mg(16)Cp*8Br(4)K](–) cluster anion (Cp* = pentamethylcy...
| Autores principales: | , , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
Royal Society of Chemistry
2016
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5530812/ https://www.ncbi.nlm.nih.gov/pubmed/28808531 http://dx.doi.org/10.1039/c5sc03914b |