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A cobalt(ii) spin-crossover compound with partially charged TCNQ radicals and an anomalous conducting behavior

The bifunctional salt [Co(terpy)(2)](TCNQ)(3)·CH(3)CN (terpy = 2,2′;6′,2′′-terpyridine, TCNQ = 7,7,8,8-tetracyanoquino-dimethane) exhibits a high room temperature conductivity of 0.13 S cm(–1) and an anomaly in conductivity at ∼190 K as evidenced by variable temperature structural, magnetic and cond...

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Detalles Bibliográficos
Autores principales:	Zhang, Xuan, Wang, Zhao-Xi, Xie, Haomiao, Li, Ming-Xing, Woods, Toby J., Dunbar, Kim R.
Formato:	Online Artículo Texto
Lenguaje:	English
Publicado:	Royal Society of Chemistry 2016
Materias:	Chemistry
Acceso en línea:	https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5530863/ https://www.ncbi.nlm.nih.gov/pubmed/28808532 http://dx.doi.org/10.1039/c5sc03547c

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