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Bimetallic iron–iron and iron–zinc complexes of the redox-active ONO pincer ligand
A new bimetallic platform comprising a six-coordinate Fe(ONO)(2) unit bound to an (ONO)M (M = Fe, Zn) has been discovered ((ONO(cat))H(3) = bis(3,5-di-tert-butyl-2-phenol)amine). Reaction of Fe(ONO)(2) with either (ONO(cat))Fe(py)(3) or with (ONO(q))FeCl(2) under reducing conditions led to the forma...
| Autores principales: | , , , , , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
Royal Society of Chemistry
2016
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5530940/ https://www.ncbi.nlm.nih.gov/pubmed/28808535 http://dx.doi.org/10.1039/c5sc03006d |