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Emergence of superconductivity in doped H(2)O ice at high pressure

We investigate the possibility of achieving high-temperature superconductivity in hydrides under pressure by inducing metallization of otherwise insulating phases through doping, a path previously used to render standard semiconductors superconducting at ambient pressure. Following this idea, we stu...

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Autores principales: Flores-Livas, José A., Sanna, Antonio, Graužinytė, Miglė, Davydov, Arkadiy, Goedecker, Stefan, Marques, Miguel A. L.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Nature Publishing Group UK 2017
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5533783/
https://www.ncbi.nlm.nih.gov/pubmed/28754909
http://dx.doi.org/10.1038/s41598-017-07145-4
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author Flores-Livas, José A.
Sanna, Antonio
Graužinytė, Miglė
Davydov, Arkadiy
Goedecker, Stefan
Marques, Miguel A. L.
author_facet Flores-Livas, José A.
Sanna, Antonio
Graužinytė, Miglė
Davydov, Arkadiy
Goedecker, Stefan
Marques, Miguel A. L.
author_sort Flores-Livas, José A.
collection PubMed
description We investigate the possibility of achieving high-temperature superconductivity in hydrides under pressure by inducing metallization of otherwise insulating phases through doping, a path previously used to render standard semiconductors superconducting at ambient pressure. Following this idea, we study H(2)O, one of the most abundant and well-studied substances, we identify nitrogen as the most likely and promising substitution/dopant. We show that for realistic levels of doping of a few percent, the phase X of ice becomes superconducting with a critical temperature of about 60 K at 150 GPa. In view of the vast number of hydrides that are strongly covalent bonded, but that remain insulating up to rather large pressures, our results open a series of new possibilities in the quest for novel high-temperature superconductors.
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spelling pubmed-55337832017-08-03 Emergence of superconductivity in doped H(2)O ice at high pressure Flores-Livas, José A. Sanna, Antonio Graužinytė, Miglė Davydov, Arkadiy Goedecker, Stefan Marques, Miguel A. L. Sci Rep Article We investigate the possibility of achieving high-temperature superconductivity in hydrides under pressure by inducing metallization of otherwise insulating phases through doping, a path previously used to render standard semiconductors superconducting at ambient pressure. Following this idea, we study H(2)O, one of the most abundant and well-studied substances, we identify nitrogen as the most likely and promising substitution/dopant. We show that for realistic levels of doping of a few percent, the phase X of ice becomes superconducting with a critical temperature of about 60 K at 150 GPa. In view of the vast number of hydrides that are strongly covalent bonded, but that remain insulating up to rather large pressures, our results open a series of new possibilities in the quest for novel high-temperature superconductors. Nature Publishing Group UK 2017-07-28 /pmc/articles/PMC5533783/ /pubmed/28754909 http://dx.doi.org/10.1038/s41598-017-07145-4 Text en © The Author(s) 2017 Open Access This article is licensed under a Creative Commons Attribution 4.0 International License, which permits use, sharing, adaptation, distribution and reproduction in any medium or format, as long as you give appropriate credit to the original author(s) and the source, provide a link to the Creative Commons license, and indicate if changes were made. The images or other third party material in this article are included in the article’s Creative Commons license, unless indicated otherwise in a credit line to the material. If material is not included in the article’s Creative Commons license and your intended use is not permitted by statutory regulation or exceeds the permitted use, you will need to obtain permission directly from the copyright holder. To view a copy of this license, visit http://creativecommons.org/licenses/by/4.0/.
spellingShingle Article
Flores-Livas, José A.
Sanna, Antonio
Graužinytė, Miglė
Davydov, Arkadiy
Goedecker, Stefan
Marques, Miguel A. L.
Emergence of superconductivity in doped H(2)O ice at high pressure
title Emergence of superconductivity in doped H(2)O ice at high pressure
title_full Emergence of superconductivity in doped H(2)O ice at high pressure
title_fullStr Emergence of superconductivity in doped H(2)O ice at high pressure
title_full_unstemmed Emergence of superconductivity in doped H(2)O ice at high pressure
title_short Emergence of superconductivity in doped H(2)O ice at high pressure
title_sort emergence of superconductivity in doped h(2)o ice at high pressure
topic Article
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5533783/
https://www.ncbi.nlm.nih.gov/pubmed/28754909
http://dx.doi.org/10.1038/s41598-017-07145-4
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