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Cultivating Fluorescent Flowers with Highly Luminescent Carbon Dots Fabricated by a Double Passivation Method
In this work, we present the fabrication of highly luminescent carbon dots (CDs) by a double passivation method with the assistance of Ca(OH)(2). In the reaction process, Ca(2+) protects the active functional groups from overconsumption during dehydration and carbonization, and the electron-withdraw...
Autores principales: | , , , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
MDPI
2017
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5535242/ https://www.ncbi.nlm.nih.gov/pubmed/28686178 http://dx.doi.org/10.3390/nano7070176 |
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author | Han, Shuai Chang, Tao Zhao, Haiping Du, Huanhuan Liu, Shan Wu, Baoshuang Qin, Shenjun |
author_facet | Han, Shuai Chang, Tao Zhao, Haiping Du, Huanhuan Liu, Shan Wu, Baoshuang Qin, Shenjun |
author_sort | Han, Shuai |
collection | PubMed |
description | In this work, we present the fabrication of highly luminescent carbon dots (CDs) by a double passivation method with the assistance of Ca(OH)(2). In the reaction process, Ca(2+) protects the active functional groups from overconsumption during dehydration and carbonization, and the electron-withdrawing groups on the CD surface are converted to electron-donating groups by the hydroxyl ions. As a result, the fluorescence quantum yield of the CDs was found to increase with increasing Ca(OH)(2) content in the reaction process. A blue-shift optical spectrum of the CDs was also found with increasing Ca(OH)(2) content, which could be attributed to the increasing of the energy gaps for the CDs. The highly photoluminescent CDs obtained (quantum yield: 86%) were used to cultivate fluorescent carnations by a water culture method, while the results of fluorescence microscopy analysis indicated that the CDs had entered the plant tissue structure. |
format | Online Article Text |
id | pubmed-5535242 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2017 |
publisher | MDPI |
record_format | MEDLINE/PubMed |
spelling | pubmed-55352422017-08-04 Cultivating Fluorescent Flowers with Highly Luminescent Carbon Dots Fabricated by a Double Passivation Method Han, Shuai Chang, Tao Zhao, Haiping Du, Huanhuan Liu, Shan Wu, Baoshuang Qin, Shenjun Nanomaterials (Basel) Article In this work, we present the fabrication of highly luminescent carbon dots (CDs) by a double passivation method with the assistance of Ca(OH)(2). In the reaction process, Ca(2+) protects the active functional groups from overconsumption during dehydration and carbonization, and the electron-withdrawing groups on the CD surface are converted to electron-donating groups by the hydroxyl ions. As a result, the fluorescence quantum yield of the CDs was found to increase with increasing Ca(OH)(2) content in the reaction process. A blue-shift optical spectrum of the CDs was also found with increasing Ca(OH)(2) content, which could be attributed to the increasing of the energy gaps for the CDs. The highly photoluminescent CDs obtained (quantum yield: 86%) were used to cultivate fluorescent carnations by a water culture method, while the results of fluorescence microscopy analysis indicated that the CDs had entered the plant tissue structure. MDPI 2017-07-07 /pmc/articles/PMC5535242/ /pubmed/28686178 http://dx.doi.org/10.3390/nano7070176 Text en © 2017 by the authors. Licensee MDPI, Basel, Switzerland. This article is an open access article distributed under the terms and conditions of the Creative Commons Attribution (CC BY) license (http://creativecommons.org/licenses/by/4.0/). |
spellingShingle | Article Han, Shuai Chang, Tao Zhao, Haiping Du, Huanhuan Liu, Shan Wu, Baoshuang Qin, Shenjun Cultivating Fluorescent Flowers with Highly Luminescent Carbon Dots Fabricated by a Double Passivation Method |
title | Cultivating Fluorescent Flowers with Highly Luminescent Carbon Dots Fabricated by a Double Passivation Method |
title_full | Cultivating Fluorescent Flowers with Highly Luminescent Carbon Dots Fabricated by a Double Passivation Method |
title_fullStr | Cultivating Fluorescent Flowers with Highly Luminescent Carbon Dots Fabricated by a Double Passivation Method |
title_full_unstemmed | Cultivating Fluorescent Flowers with Highly Luminescent Carbon Dots Fabricated by a Double Passivation Method |
title_short | Cultivating Fluorescent Flowers with Highly Luminescent Carbon Dots Fabricated by a Double Passivation Method |
title_sort | cultivating fluorescent flowers with highly luminescent carbon dots fabricated by a double passivation method |
topic | Article |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5535242/ https://www.ncbi.nlm.nih.gov/pubmed/28686178 http://dx.doi.org/10.3390/nano7070176 |
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