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Cultivating Fluorescent Flowers with Highly Luminescent Carbon Dots Fabricated by a Double Passivation Method

In this work, we present the fabrication of highly luminescent carbon dots (CDs) by a double passivation method with the assistance of Ca(OH)(2). In the reaction process, Ca(2+) protects the active functional groups from overconsumption during dehydration and carbonization, and the electron-withdraw...

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Autores principales: Han, Shuai, Chang, Tao, Zhao, Haiping, Du, Huanhuan, Liu, Shan, Wu, Baoshuang, Qin, Shenjun
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2017
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5535242/
https://www.ncbi.nlm.nih.gov/pubmed/28686178
http://dx.doi.org/10.3390/nano7070176
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author Han, Shuai
Chang, Tao
Zhao, Haiping
Du, Huanhuan
Liu, Shan
Wu, Baoshuang
Qin, Shenjun
author_facet Han, Shuai
Chang, Tao
Zhao, Haiping
Du, Huanhuan
Liu, Shan
Wu, Baoshuang
Qin, Shenjun
author_sort Han, Shuai
collection PubMed
description In this work, we present the fabrication of highly luminescent carbon dots (CDs) by a double passivation method with the assistance of Ca(OH)(2). In the reaction process, Ca(2+) protects the active functional groups from overconsumption during dehydration and carbonization, and the electron-withdrawing groups on the CD surface are converted to electron-donating groups by the hydroxyl ions. As a result, the fluorescence quantum yield of the CDs was found to increase with increasing Ca(OH)(2) content in the reaction process. A blue-shift optical spectrum of the CDs was also found with increasing Ca(OH)(2) content, which could be attributed to the increasing of the energy gaps for the CDs. The highly photoluminescent CDs obtained (quantum yield: 86%) were used to cultivate fluorescent carnations by a water culture method, while the results of fluorescence microscopy analysis indicated that the CDs had entered the plant tissue structure.
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spelling pubmed-55352422017-08-04 Cultivating Fluorescent Flowers with Highly Luminescent Carbon Dots Fabricated by a Double Passivation Method Han, Shuai Chang, Tao Zhao, Haiping Du, Huanhuan Liu, Shan Wu, Baoshuang Qin, Shenjun Nanomaterials (Basel) Article In this work, we present the fabrication of highly luminescent carbon dots (CDs) by a double passivation method with the assistance of Ca(OH)(2). In the reaction process, Ca(2+) protects the active functional groups from overconsumption during dehydration and carbonization, and the electron-withdrawing groups on the CD surface are converted to electron-donating groups by the hydroxyl ions. As a result, the fluorescence quantum yield of the CDs was found to increase with increasing Ca(OH)(2) content in the reaction process. A blue-shift optical spectrum of the CDs was also found with increasing Ca(OH)(2) content, which could be attributed to the increasing of the energy gaps for the CDs. The highly photoluminescent CDs obtained (quantum yield: 86%) were used to cultivate fluorescent carnations by a water culture method, while the results of fluorescence microscopy analysis indicated that the CDs had entered the plant tissue structure. MDPI 2017-07-07 /pmc/articles/PMC5535242/ /pubmed/28686178 http://dx.doi.org/10.3390/nano7070176 Text en © 2017 by the authors. Licensee MDPI, Basel, Switzerland. This article is an open access article distributed under the terms and conditions of the Creative Commons Attribution (CC BY) license (http://creativecommons.org/licenses/by/4.0/).
spellingShingle Article
Han, Shuai
Chang, Tao
Zhao, Haiping
Du, Huanhuan
Liu, Shan
Wu, Baoshuang
Qin, Shenjun
Cultivating Fluorescent Flowers with Highly Luminescent Carbon Dots Fabricated by a Double Passivation Method
title Cultivating Fluorescent Flowers with Highly Luminescent Carbon Dots Fabricated by a Double Passivation Method
title_full Cultivating Fluorescent Flowers with Highly Luminescent Carbon Dots Fabricated by a Double Passivation Method
title_fullStr Cultivating Fluorescent Flowers with Highly Luminescent Carbon Dots Fabricated by a Double Passivation Method
title_full_unstemmed Cultivating Fluorescent Flowers with Highly Luminescent Carbon Dots Fabricated by a Double Passivation Method
title_short Cultivating Fluorescent Flowers with Highly Luminescent Carbon Dots Fabricated by a Double Passivation Method
title_sort cultivating fluorescent flowers with highly luminescent carbon dots fabricated by a double passivation method
topic Article
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5535242/
https://www.ncbi.nlm.nih.gov/pubmed/28686178
http://dx.doi.org/10.3390/nano7070176
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