Cargando…

A Sustainable Nanocomposite Au(Salen)@CC for Catalytic Degradation of Eosin Y and Chromotrope 2R Dyes

Up to now, a very few catalysts have been developed approaching the heterogeneous catalytic degradation of Eosin Y and Chromotrope 2R dyes (Acid Red 29). The present study provides a complete perspective of recyclable nanocomposite Au(Salen)@CC for catalytic degradation of hazardous water pollutant...

Descripción completa

Detalles Bibliográficos
Autores principales: Mayani, Vishal J., Mayani, Suranjana V., Kim, Sang Wook
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Nature Publishing Group UK 2017
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5543062/
https://www.ncbi.nlm.nih.gov/pubmed/28775270
http://dx.doi.org/10.1038/s41598-017-07707-6
_version_ 1783255080376467456
author Mayani, Vishal J.
Mayani, Suranjana V.
Kim, Sang Wook
author_facet Mayani, Vishal J.
Mayani, Suranjana V.
Kim, Sang Wook
author_sort Mayani, Vishal J.
collection PubMed
description Up to now, a very few catalysts have been developed approaching the heterogeneous catalytic degradation of Eosin Y and Chromotrope 2R dyes (Acid Red 29). The present study provides a complete perspective of recyclable nanocomposite Au(Salen)@CC for catalytic degradation of hazardous water pollutant dyes viz., Eosin Y & Chromotrope 2R using mild reaction conditions. New gold Salen complex doped carbon nanocomposite Au(Salen)@CC was developed by easy methodology using nano carbon cage (CC) prepared from low-priced Pyrolysis fuel oil (PFO) residue based Pitch. The UV-Vis adsorption spectroscopy results of Eosin Y and Chromotrope 2R dyes indicated complete degradation into acidic compounds which can be further mineralized to CO(2) and H(2)O under mild reaction conditions. The heterogeneous catalyst recycled and reused successfully for four repeated experiments without loss in its adequate performance. This new sustainable and eco-friendly catalyst delivered significant degradation activity compared to existing reports and it can be further utilized for new multifunctional applications such as, radiopharmaceutical activities, heterogeneous catalysis and chiral resolution.
format Online
Article
Text
id pubmed-5543062
institution National Center for Biotechnology Information
language English
publishDate 2017
publisher Nature Publishing Group UK
record_format MEDLINE/PubMed
spelling pubmed-55430622017-08-07 A Sustainable Nanocomposite Au(Salen)@CC for Catalytic Degradation of Eosin Y and Chromotrope 2R Dyes Mayani, Vishal J. Mayani, Suranjana V. Kim, Sang Wook Sci Rep Article Up to now, a very few catalysts have been developed approaching the heterogeneous catalytic degradation of Eosin Y and Chromotrope 2R dyes (Acid Red 29). The present study provides a complete perspective of recyclable nanocomposite Au(Salen)@CC for catalytic degradation of hazardous water pollutant dyes viz., Eosin Y & Chromotrope 2R using mild reaction conditions. New gold Salen complex doped carbon nanocomposite Au(Salen)@CC was developed by easy methodology using nano carbon cage (CC) prepared from low-priced Pyrolysis fuel oil (PFO) residue based Pitch. The UV-Vis adsorption spectroscopy results of Eosin Y and Chromotrope 2R dyes indicated complete degradation into acidic compounds which can be further mineralized to CO(2) and H(2)O under mild reaction conditions. The heterogeneous catalyst recycled and reused successfully for four repeated experiments without loss in its adequate performance. This new sustainable and eco-friendly catalyst delivered significant degradation activity compared to existing reports and it can be further utilized for new multifunctional applications such as, radiopharmaceutical activities, heterogeneous catalysis and chiral resolution. Nature Publishing Group UK 2017-08-03 /pmc/articles/PMC5543062/ /pubmed/28775270 http://dx.doi.org/10.1038/s41598-017-07707-6 Text en © The Author(s) 2017 Open Access This article is licensed under a Creative Commons Attribution 4.0 International License, which permits use, sharing, adaptation, distribution and reproduction in any medium or format, as long as you give appropriate credit to the original author(s) and the source, provide a link to the Creative Commons license, and indicate if changes were made. The images or other third party material in this article are included in the article’s Creative Commons license, unless indicated otherwise in a credit line to the material. If material is not included in the article’s Creative Commons license and your intended use is not permitted by statutory regulation or exceeds the permitted use, you will need to obtain permission directly from the copyright holder. To view a copy of this license, visit http://creativecommons.org/licenses/by/4.0/.
spellingShingle Article
Mayani, Vishal J.
Mayani, Suranjana V.
Kim, Sang Wook
A Sustainable Nanocomposite Au(Salen)@CC for Catalytic Degradation of Eosin Y and Chromotrope 2R Dyes
title A Sustainable Nanocomposite Au(Salen)@CC for Catalytic Degradation of Eosin Y and Chromotrope 2R Dyes
title_full A Sustainable Nanocomposite Au(Salen)@CC for Catalytic Degradation of Eosin Y and Chromotrope 2R Dyes
title_fullStr A Sustainable Nanocomposite Au(Salen)@CC for Catalytic Degradation of Eosin Y and Chromotrope 2R Dyes
title_full_unstemmed A Sustainable Nanocomposite Au(Salen)@CC for Catalytic Degradation of Eosin Y and Chromotrope 2R Dyes
title_short A Sustainable Nanocomposite Au(Salen)@CC for Catalytic Degradation of Eosin Y and Chromotrope 2R Dyes
title_sort sustainable nanocomposite au(salen)@cc for catalytic degradation of eosin y and chromotrope 2r dyes
topic Article
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5543062/
https://www.ncbi.nlm.nih.gov/pubmed/28775270
http://dx.doi.org/10.1038/s41598-017-07707-6
work_keys_str_mv AT mayanivishalj asustainablenanocompositeausalenccforcatalyticdegradationofeosinyandchromotrope2rdyes
AT mayanisuranjanav asustainablenanocompositeausalenccforcatalyticdegradationofeosinyandchromotrope2rdyes
AT kimsangwook asustainablenanocompositeausalenccforcatalyticdegradationofeosinyandchromotrope2rdyes
AT mayanivishalj sustainablenanocompositeausalenccforcatalyticdegradationofeosinyandchromotrope2rdyes
AT mayanisuranjanav sustainablenanocompositeausalenccforcatalyticdegradationofeosinyandchromotrope2rdyes
AT kimsangwook sustainablenanocompositeausalenccforcatalyticdegradationofeosinyandchromotrope2rdyes