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In situ generation of N-unsubstituted imines from alkyl azides and their applications for imine transfer via copper catalysis

Although azides have been widely used in nitrene transfer reactions, in situ generation of N-H imines from azides for downstream transformations has rarely been explored. We report copper-mediated formation of N-unsubstituted aliphatic imines from easily available aliphatic azides using a customized...

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Detalles Bibliográficos
Autores principales: Hu, Lu, Liu, Yahu A., Liao, Xuebin
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Association for the Advancement of Science 2017
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5550227/
https://www.ncbi.nlm.nih.gov/pubmed/28808683
http://dx.doi.org/10.1126/sciadv.1700826